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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of agricultural and food chemistry 41 (1993), S. 1936-1940 
    ISSN: 1520-5118
    Source: ACS Legacy Archives
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Zeitschrift für Lebensmittel-Untersuchung und -Forschung 208 (1999), S. 400-407 
    ISSN: 1431-4630
    Keywords: Key words Wine ; Oxygen isotopes ; Adulteration control ; Origin assignment ; European Union data bank
    Source: Springer Online Journal Archives 1860-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract  The application of oxygen isotope analysis to wine water (according to EU regulation no. 822/97) to determine a wine's origin, and check that it has not been adulterated is gaining increasing importance in both laboratories and industry. Using samples of Italian, French and German wines from the EU wine data bank (EU-DB), good agreement between the results from participating laboratories was demonstrated. Close correlations between the oxygen isotope contents of must and related wine water were found for samples from all countries. Based on the results of the δ18O values for EU-DB wines from 1991 to 1996 from Italy, France and Germany, we describe and discuss the main factors which are responsible for the variation of the oxygen isotope ratios of wine water. The examination of spiked samples demonstrated the usefulness of δ18O analysis for the detection of the watering down of wine. The possibility of origin assignment, preferably if the determination of the δ18O value by isotope ratio mass spectrometry (IRMS) is employed together with the determination of the site-specific hydrogen isotope content of wine ethanol by 2H-NMR and the measurement of δ13C values of ethanol by IRMS, is outlined.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Soil Science Society of America journal 64 (2000), S. 639-645 
    ISSN: 1435-0661
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: 13 C–nuclear magnetic resonance spectra (13C–NMR), we studied δ13C values and biochemical activities of the humic constituents extracted from the Ah horizons of two undisturbed forest soils, located in a unique climatic area under different vegetative covers, Pinus mugo T. and Pinus sylvestris L. The two litters differed greatly in composition, while the 13C–NMR spectra of the humic substances extracted from the two Ah horizons were similar. The 13C–NMR spectra of the low molecular humic size (LMS) 1–2 revealed high aromatic and carboxylic contents and low aliphatic and carbohydratic ones. The total humic extracts (TQ) 1–2 and the high molecular humic size (HMS) 1–2 exhibited an opposite trend. The δ13C values of the humic fractions ranged from −24.96 to −25.84‰, indicating an advanced stage of humification. The biochemical activities of the humic fractions were studied by evaluating the invertase, peroxidase, and esterase activities in Pinus mugo and Pinus sylvestris seedling roots grown in the presence of their humic matter. These forest species were differently affected by their humic substances. In particular, the Pinus sylvestris humic matter, endowed with a higher indoleacetic acid (IAA) content, positively influenced all the enzymes tested in Pinus sylvestris seedlings, while the Pinus mugo humic matter only increased the peroxidase activity in its seedlings. The plant species differ in their capacity to respond to biological humus activity, which is reflected in their natural distribution.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-5036
    Keywords: δ 13C ; humic fractions ; invertase and peroxidase activities ; NMR spectra ; root hairs ; scanning electron micrograph ; wheat roots
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The chemical and biological characteristics of humus within the Ah horizon (Calcic-Luvisol) have been studied. Attention was paid to variation in the NMR spectra of humic fractions and δ 13C values and to how these changes are related to different biological humic fraction activities. The chemical changes in particular involve the decrease of the aromatic component and the increase of the non-aromatic component within the horizon and the different δ 13C value not only within the horizon but also among the humic fractions distinctive of different molecular sizes. An attempt has been made to explain the vertical chemical changes in terms of processes affecting the biological characteristics of the high and low molecular size humic fractions. The main conclusions are that the low molecular size humic fractions, in the upper part of the horizon, are of greater importance with respect to the other humic fractions in influencing the enzyme activities linked to growth metabolism. The biological role of the high molecular size humic fractions characterised by a relevant content of peptidic- and carbohydratic-C is also presented.
    Type of Medium: Electronic Resource
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