ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Directed Synthesis of Sulfinato-O and -S Complexes of Some Transition Metals, XIV Sulfinato-O,S Complexes of Palladium(II) and Rhodium(III)The directed preparation of the sulfinato-O,S complexes {R(O)OS}nM (2a, b; 5a, b) was successful for the first time by elimination of coordinated water from the sulfinato-S complexes {RS(O)2}nM(OH2)n [n = 2, M = Pd (1a, b); n = 3, M = Rh (4a, b)] by 2,2-dimethoxypropane. The O,S-linkage is unequivocally shown from their chemical behaviour and the i. r. spectra. The criteria necessary for the formation of sulfinato-O,S complexes are discussed.
Notes:
Durch Abspaltung von koordiniertem Wasser aus den Sulfinato-S-Komplexen {RS(O)2}nM(OH2)n [n = 2, M = Pd (1a, b); n = 3, M = Rh (4a, b)] mit 2,2-Dimethoxypropan gelang erstmals die gezielte Darstellung der Sulfinato-O,S-Komplexe {R(O)OS}nM (2a, b; 5a, b). Die O,S-Verknüpfung ergibt sich eindeutig aus dem chemischen Verhalten und den IR-Spektren. Die für die Bildung von Sulfinato-O,S-Komplexen notwendigen Kriterien werden diskutiert.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19771100208
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