ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The condensation of hydrochloric salts of ω-aminomethyl aryl ketones with diphenic anhydride or with the diacid chloride of diphenic acid and subsequent cyclodehydration of the condensation products formed give sterically hindered mono- and bis(2, 5-diaryloxazoles) containing the biphenyl system. The spectroluminescent properties of these compounds were studied. Comparison of the absorption spectra of 2,2′-di(5-phenyloxazolyl-2)biphenyl and 2,5-diphenyloxazole indicates the complete lack of conjugation between the diphenyloxazole fragments, their independent behavior, and their retention of the spatial configuration of 2,5-diphenyloxazole. 2,2′-Di(5-phenyloxazolyl-2)biphenyl has a large Stokes shift. Steric hindrance is also found in 2-carboxy-2′-(5-phenyloxazolyl-2)biphenyl molecules.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00504197
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