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  • 1
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 317-318 (Aug. 2006), p. 469-472 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The contact deformation mechanisms of a superplastic ceramic, 3Y-TZP (3mol %yttria-partially stabilized tetragonal zirconia polycrystals) are examined in indentation creep tests athigh temperatures. A large discrepancy between the uniaxial compression and the pyramidalindentation contact behaviors is observed. The indentation creep curves exhibit a hardening behavior,i.e., the penetration rate decreases as the penetration depth and/or the creep time increases. This factimplied that the cooperative grain-boundary sliding (CGBS) in a microscopically localized region,such as the sub-surface contact region beneath a pyramidal indenter, is very limited through themicroscopic processes of localized grain interlocking
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Anatase nanocrystals were formed on sol-gel derived SiO2-TiO2 coatings with water vaporor hot water treatments. The anatase nanocrystals were precipitated through hydrolysis of Si-O-Tibonds, dissolution of SiO2 component, migration of hydrolyzed titania species, and nucleation andgrowth. The process temperatures can be lowered below 60oC, which should open new applications.It was found that the crystal habit of titania was changes from roundish anatase to sheet-like titania byapplying vibration during the hot water treatment. The nanosheets were identified as hydrated titania,TiO2 . mH2O, with layerd structure. The coatings of hydrated titania showed high photocatalyticactivities and excellent antifogging properties due to their unique morphology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 317-318 (Aug. 2006), p. 677-682 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Preparation of monodispersed inorganic-organic hybrid particles has become one of themost attractive research topics in recent years. In this study, phenylsilsesquioxane (PhSiO3/2) particleswere synthesized from phenyltriethoxysilane (PhSi(OEt)3), ethanol (EtOH), hydrochloric acid forhydrolysis and ammonia water for polycondensation by the sol-gel method. Spherical PhSiO3/2particles were obtainable by varying the mole ratios of EtOH, H2O, HCl and NH3, to PhSi(OEt)3. Theparticle size was changed from 0.1 to 5.0 .m with the mole ratio. Under the optimum conditions,monodispersed particles with 1.50 .m in diameter and 0.05 of normalized standard deviation weresuccessfully prepared
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 137 (Apr. 1997), p. 9-15 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 161-163 (July 1998), p. 397-400 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The time-dependent viscoelastic deformation and flow of various types of silicate glasses are examined by the use of a pyramidal Berkovich indenter. It is demonstrated that a pyramidal indenter is an efficient microprobe for viscoelastic studies of glass-forming materials at temperatures near the glass transition point. Some important rheological functions of silicate glasses are determined as functions of time on the basis of a linear viscoelastic constitutive equation for pyramidal indentation. The test results are theoretically related to the dimension of flow units of these glasses, suggesting that a model of thermally fragmented silicate clusters is appropriate for consistently understanding the present rheological test results. However, the microstructural details (crystallite-like or network-like microstructures) of fragmented clusters are not inferred from the rheological information.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A Vickers indenter, as an efficient mechanical microprobe, was applied to carbon materials heat-treated at temperatures in the range 880°–2600°C. The plasticity of the carbon materials, which was enhanced by increasing the heat-treatment temperature (HTT), was assessed from the relation between the indentation load, P, and the penetration depth, h. Using the concept of the true hardness, H, as a measure of plasticity and the experimental estimate of the H-value, the plasticity of the carbon materials was examined as a function of their crystallographic parameters. The residual impression of the carbons at HTT 〉 1800°C was hardly visible on the indented surface after unloading, because of the nearly complete elastic recovery of the indented surface, yielding a very unique indentation P–h hysteresis in the loading/unloading cycle. The microscopic processes associated with this unique elastic recovery during unloading are discussed here in relation to the reversible slip of the dislocation-network structures on the graphitic basal planes.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crack bridging associated with the pull-out process of interlocking grains in self-reinforced ceramic materials is studied through a micromechanical simulation. The pullout of a single inclined grain is modeled via the numerical solution of a general contact problem. The bridging-force versus crack-opening-distance curve indicates a nonlinear, springlike response for the pullout of interlocking grains. The sliding friction along the debonded interface, induced by highly localized contact stresses, dominates the total bridging force. The bridging force increases with grain inclination until eventual bridge failure. The pullout of misaligned grains mainly affects short-crack toughening, with a rising R-curve, whereas aligned grains contribute to long-crack toughening. The residual stresses of the thermal expansion anisotropy play a minor role in the pull-out process of grain interlocking and the resultant toughening. The proposed mechanism is operative in both single-phase and composite ceramics in which pullout of elongated grains/reinforcements occurs.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Grain-boundary sliding and grain interlocking of two-phase ceramics during creep are examined on the basis of the Dryden–Kucerovsky–Wilkinson–Watt theory. That theory is extended to the plane–strain creep deformation of model arrays of square and hexagonal grains embedded in a continuous grain-boundary melt phase to develop consti-tutive equations for their universal creep. Superposition is derived for the “time-applied stress” and the “time–temperature” relations during creep. The “shift factor” for the time–temperature superposition characterizes the temperature dependence of the apparent viscosity of the ceramic. A two-phase ceramic during creep acts as a non-Newtonian fluid, the viscosity of which is dependent on the creep strain. The constitutive relation between the creep strain rate and the creep strain is then utilized to estimate the viscosity and the volume fraction of the intergranular melt phase. The equilibrium creep strain to achieve grain interlocking is considered through the rotational motion of grains. Creep tests for a β-spodumene glass-ceramic are conducted under simple shear to generate experimental results for scrutinizing the theoretical predictions. Satisfactory agreement is observed, giving important rheological information on the creep process.
    Type of Medium: Electronic Resource
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