ISSN:
1434-1948
Keywords:
Hydroformylations
;
Rare gas
;
Homogeneous catalysis
;
Carbonylcobalt compounds
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The rate of cobalt-catalyzed hydroformylation of cyclohexene to cyclohexanecarboxaldehyde is significantly reduced when xenon is added to the reaction mixture at a concentration similar to that of the olefin. No significant effect is produced by helium or neon under similar conditions. These experiments suggest competitive coordination of xenon to the catalytically active cobalt species.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
Permalink