ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and X-Ray Structure Determination of [InCl4(H2O)2][S4N3] - a Tetrachloro-cis-diaqua Complex of Indium(III)The compounds [InCl4(H2O)2][S4N3] (I) and In2Cl8H2O(S4N3)2 (II) were synthesized and the structure of the former determined by x-ray methods. The compound crystallizes in the space group D2h16-Pnam, the unit cell dimensions are a = 19.473 ± 0.003 Å, b = 6.183 ± 0.003 Å, c = 10.814 ± 0.003 Å. Least squares refinement has reached R = 4.9%.
Notes:
Die Verbindungen [InCl4(H2O)2][S4N3] (I) und In2Cl8H2O(S4N3)2 (II) wurden dargestellt und die Struktur der ersteren mittels Röntgenstrukturanalyse bestimmt. Die Verbindung kristallisiert in der Raumgruppe D2h16 - Pnam mit den Gitterkonstanten a = 19,473 ű 0,003 Å, b = 6,183 ± 0,003 Å, c = 10,814 ± 0,003 Å. Die Verfeinerung nach der Methode der kleinsten Quadrate ergab einen R-Wert von 4,9%.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19754150302
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