ISSN:
1432-2234
Keywords:
d 6 configuration
;
Ligand Field Theory
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The formation of spin triplet, quintet, and singlet ground states within the 3d 6 electron configuration is investigated inD 4h , andD 3d symmetries employing irreducible tensor operator methods. Significant differences in the possible ground states are encountered between a complete CI and spin-orbit interaction treatment and an approximate calculation within the cubic5 T 2,1A1,3 T 1, and3 T 2 parents.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01209768
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