Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Bingley : Emerald
    International journal of clothing science & technology 7 (1995), S. 17-35 
    ISSN: 0955-6222
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Provides a survey about a new process for dyeing synthetic fibres and fabrics. The use of disperse dyes in supercritical carbon dioxide as a dyeing medium completely avoids water pollution and the need for drying. Presents laboratory results showing excellent levelness and fastnesses on the dyeing of polyethylene terephthalate and on polyamides. Describes the state of technical development.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 5221-5223 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The concept of photothermal wave imaging has been adapted to the nondestructive inspection of transparent polymeric samples by specific generation of thermal waves. Utilization of light sources according to the absorption properties of the material secured pure surface heating which is necessary for sensible measurements. Thickness profiles of thin films made of poly(ethylene terephthalate), which are transparent in the visible spectrum, could be measured using a pulsed KrF laser. Examples for the nondestructive inspection of complex textile samples such as coated fabrics are presented.The photothermal analysis (PTA) of optically generated thermal waves is a powerful tool for nondestructive, contactless inspection and evaluation of intrinsic properties of a sample.1,2 The method has been used for the observation of dynamic processes in adhesives, for the inspection of coatings on metal and of carbon fiber composites. A modulated light source, e.g., a chopped HeNe- or Ar+ laser, is used for local, modulated heating at the sample's surface resulting in a time- and space-dependent temperature modulation which propagates through the material. In the case of a homogeneous layer heated only in a small volume at the surface the solution of the heat diffusion equation gives a heavily damped thermal wave T(x,y,z;t). In a one-dimensional model3 only the direction z perpendicular to the surface is considered and we obtain
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 1854-1858 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects on chemical and physical properties due to microstructuring of poly(ethyleneterephthalate) (PETP) fiber surfaces by uv-laser treatment are investigated. Data are given about a slight color change at the irradiated sites of laser-treated fabrics in relation to the amount of debris deposited under ablating conditions. The debris formed under irradiation in air consists of carbonlike particles. Evidence is given for the pure pyrolytic nature of uv-laser ablation of PETP at 248 nm by using laser desorption mass spectroscopy. Chemical modification of the surface, yielding some carboxylic groups, an increased O-to-C ratio, and a small change of the crystallinity of the fiber surface is detected using x-ray-induced photoelectron spectroscopic and Fourier-transform infrared analysis.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 1884-1886 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Excimer-laser-induced ablation of polymers is often accompanied by a modification of the surface morphology at the irradiated regions. Only very recently models have been proposed for this effect, the origin being searched in different absorption properties of crystalline and amorphous material. A study by the authors on synthetic fibers irradiated by the UV laser is in contrast with that assumption and gave evidence of a thermal contribution to laser-polymer interaction. Furthermore, a strong influence of internal or external stress fields is found. On this basis a synergetic understanding of the surface structures is proposed.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 1572-8927
    Keywords: Crown ethers ; benzocrown ethers ; non-charged complexes ; host-guest complexes ; calorimetric titration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The formation of complexes between crown ethers and acetonitrile, chloroform, and nitromethane were investigated in carbon tetrachloride at 25°C. A significant influence of the ring size on the selectivity of the host is evident. The host 18-crown-6 forms complexes for which the reaction enthalpy and entropy are quite high. Host molecules with benzene side groups form complexes of lower reaction enthalpy and entropy and therefore the complexes formed are less stable than that of the analogous crown ethers without aromatic groups. Solvent effects on the stability constant K, the reaction enthalpy ΔH, and the reaction entropy ΔS were studied for the complexation of malonitrile by 18-crown-6. The reaction enthalpy and entropy values change in accordance with the dielectric constant of the solvent used, but no overall effect on complex stability with change in solvent dielectric constant was observed.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 75 (1979), S. 79-97 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zeta-potentials afford an insight into the polymer/liquid interface. However, they cannot be measured directly but have to be calculated from the streaming current, the streaming resistance and the electrical resistance yielded from electrokinetic measurements by means of a model suitable to describe the porous plug.Besides the description of an experimental arrangement for electrokinetic measurements with fibres it is the aim of this contribution to apply this method to problems in textile chemistry by some examples.
    Notes: Zetapotentiale geben einen Einblick in die Polymer-Flüssigkeits-Phasengrenzfläche. Sie können jedoch nicht auf direktem Wege experimentell ermittelt werden, sondern errechnen sich aus den bei elektrokinetischen Untersuchungen erhaltenen Strömungsströmen, Strömungswiderständen und Ohmschen Widerständen mit Hilfe eines zur Beschreibung des porösen Feststoffpfropfens geeignet erscheinenden Modells.Ziel dieser Arbeit ist es, neben der Beschreibung einer experimentellen Anordnung für elektrokinetische Untersuchungen an Fasern die Anwendung der Methode auf textilchemische Fragestellungen aufzuzeigen.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 7
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: One constitutive property for the description of dyeing polyester-materials with disperse dyes is the particle size distribution in the dye bath. To measure particle sizes below one micrometer in situ, special techniques are required. One of these is the so called photon-correlation-spectroscopy, depending on the scattering of laser light by suspended small particles in a fluid. The mathematical and physical principles of the photon-correlation-technique are explained in this article.
    Notes: Eine zur Beschreibung des Färbevorganges von Polyestermaterialien mit Dispersionsfarbstoffen wesentliche Größe stellt die Partikelgrößenverteilung im Farbebad dar. Partikelgrößen unterhalb eines Mikrometers lassen sich in situ nur mit wenigen Meßtechniken bestimmen. Dazu zählt u. a. die Photonen-Korrelations-Spektroskopie, die auf Streuung von Laserlicht an kleinen, in einer Flüssigkeit suspendierten Teilchen basiert. Die mathematischen und physikalischen Grundlagen dieser Meßtechnik werden in diesem Artikel erläutert.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 8
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The UV-laser induced surface modification of various types of high-performance fibers is investigated. Due to the high UV-absorption coefficients, the well-known effect of UV-laser induced etching (ablation) is observed with all fiber types. Furthermore, the relaxation of orientated macromolecules leads to a characteristic structuring of the fiber surface. For a possible controlled use of this physical surface modification, exact conditions for the treatment in view of textile applications are determined. Useful constants like threshold of ablation, etching rate and structuring constants are measured for all fiber types.
    Notes: Die Oberflächenbehandlung von unterschiedlichen Hochleistungsfasertypen mit gepulstem UV- Laserlicht wird untersucht. Bedingt durch die hohen UV-Absorptionskoeffizienten dieser Materialien wird der bekannte Effekt des UV-laserinduzierten Abtrags (Ablation) bei allen Fasern beobachtet. Zusätzlich werden durch die Relaxation der orientierten Makromoleküle charakteristische Strukturierungen auf der Faseroberfläche ausgebildet. Für einen möglichen kontrollierten und gezielten Einsatz dieser physikalischen Oberflächenmodifizierung in textilen Anwendungen werden die gnaunen Bedingungen der Laserbestrahlung ermittelt und beschieben. Darüber hinaus werden geeignete Konstanten der Laserbearbeitung wie Ablationsschwellenenergie, Ätzraten und Strukturierungskonstanten für verschiedene Fasertypen bestimmt.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 234 (1996), S. 159-175 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: The evaluation of the viscoelastic response of synthetic fibres from stress-relaxation data over a wide range of time at different strain rates is very time-consuming. Therefore, mathematical models are used to describe the viscoelastic response. The characteristic of synthetic fibres is that already at very low deformation rates like an elongation 〈 1% a nonlinear viscoelasticity has to be considered.Based on the analytical representation of isothermal viscoelastic behaviour by Boltzmann a new model making an assertion to the nonlinear viscoelasticity is proposed. Applying this model, the calculated values of moduli and relaxation tensions of the fibres Nomex® and PEEK are in good agreement with the experimental values.
    Notes: Zur Beurteilung des viskoelastischen Verhaltens von Synthesefasern sind zeitaufwendige Relaxationsuntersuchungen erforderlich. Um zu schnelleren Aussagen zu gelangen, werden mathematische Modelle benötigt. Charakteristisch für Synthesefasern ist, daß bereits bei sehr kleinen Dehnungen 〈 1% kein lineares viskoelastisches Verhalten angenommen werden kann. Es wird ein auf der Grundlage der Boltzmann-Theorie erweitertes Modell vorgestellt, welches das nichtlineare viskoelastische Verhalten von Synthesefasern beschreibt. Unter Anwendung des hier vorgestellten Modells wird das Relaxationsverhalten der Synthesefasern Nomex® und PEEK beschrieben und ein Konzept zur Messung und Auswertung des Ergebnisses vorgestellt.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 128 (1984), S. 15-45 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Density and orientation describe, besides other characteristics, the structure of high polymers. They can be obtained as a function of the radius by measurement of the refraction index of the fibre.The influence of refraction of light on the obtained index of refraction n(r) is demonstrated by an optical model of the fibre. For fibres having a radius R 〈 30 μm and changes in the refraction index 〈 0.02 the influence of refraction is less than ± 0.0002 and therefore of no significance for most textile fibres. Important is the exact adaption of the refraction index of the embeding medium to the margin of the fibre. The computed index at the margin of the fibre takes always the refraction index of the embeding medium. An incorrect adaption can be traced up to 0.2·R into the fibre.A spline function used for the approximation of the relative displacement of interference fringes gives the opportunity to calculate extreme variations in refractive index, this is demonstrated using hollow fibres filled with paraffin-oil. Using a HeNe-laser interference-holographie became possible.
    Notes: Dichte und Orientierung sind wichtige Größen für die Strukturaufklärung von Hochpolymeren. Diese lassen sich bei Fasern durch Brechwertmessung als Funktion des Radius gewinnen.Der Einfluß der Lichtbrechung auf den Brechwertverlauf n(r) wird mit Hilfe eines optischen Modells der Faser berechnet. Er ist für Fasern mit einem Radius R 〈 30 μm und Brechwertschwankungen 〈 0,02 kleiner als ± 0,0002 und ist deshalb für textile Fasern im allgemeinen ohne Bedeutung. Wichtiger ist die genaue Anpassung der Einbettungsimmersion an den Faserrand: Der berechnete Brechwertverlauf nimmt am Faserrand stets den Brechwert der Einbettung an, wobei sich der Einfluß der Fehlanpassung ca. 0,2 · R in die Faser zurückverfolgen läßt.Mit Hilfe einer Spline-Funktion als Näherung für die Interferenzstreifenversetzung werden auch extreme Brechwertverläufe gut wiedergegeben; als Beispiel wird der Brechwert der Füllung einer Glashohlfaser untersucht.Durch Verwendung eines HeNe-Lasers als Lichtquelle des Interferenzmikroskopes ist die Anwendung der Interferenz-Holographie möglich.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...