ISSN:
1662-9752
Source:
Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
The crystal structure of new Prussian blue analogue samples,KCu[Fe〈sub〉1-x〈/sub〉 Co〈sub〉x〈/sub〉(CN)〈sub〉6〈/sub〉], KNi[Fe〈sub〉1-x〈/sub〉 Co〈sub〉x〈/sub〉(CN)〈sub〉6〈/sub〉] and Fe[Fe〈sub〉1-x〈/sub〉 Co〈sub〉x〈/sub〉(CN)〈sub〉6〈/sub〉], was solved on the base of the model from Keggin and Miles [1] and refined by the Rietveld method [2] from conventional X-raypowder diffraction data. These compounds form mixed crystals for all Fe/Co ratios. The crystal structure of the KCu[Fe〈sub〉0.3〈/sub〉Co〈sub〉0.7〈/sub〉(CN)〈sub〉6〈/sub〉], KNi[Fe〈sub〉0.3〈/sub〉Co〈sub〉0.7〈/sub〉(CN)〈sub〉6〈/sub〉] and Fe[Fe〈sub〉0.8〈/sub〉Co〈sub〉0.2〈/sub〉(CN)〈sub〉6〈/sub〉] is presented in detail. For both potassium containing compounds the disorder in the potassium arrangement is the most obvious characteristic
Type of Medium:
Electronic Resource
URL:
http://www.tib-hannover.de/fulltexts/2011/0528/02/07/transtech_doi~10.4028%252Fwww.scientific.net%252FMSF.443-444.345.pdf
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