ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1,1,1,4,5,5,5-Heptafluoro-4-(trifluoromethyl)-2,3-pentanedione reacted with λ3σ3-phosphorus compounds, PR1R2R3 (R1 = CF3, R2 = R3 = Me, iPr, NEt2; R1 = NCO, R2 = R3 = OMe, OEt, R2-R3 = OCH2CH2O, OCMe2CMe2O; R1 = OSiMe3, R2 = R3 = OEt; R1 = NEt2, R2 = R3 = OCH2CF3; R1 = R2 = Et2N, R3 = OCH2CF3, OCH(CF3)2, OCH2Ph, OC6F5) to give new 1,3,2λ5σ5-dioxaphospholenes. The first λ5σ5 phosphoranes with an OCN group bonded to phosphorus were obtained. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:109-113, 1998
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
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