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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 8 (1994), S. 829-832 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Despite the widespread use of matrix-assisted laser desorption ionization, the processes involved in ion formation have yet to be satisfactorily explained. Several protonation processes have been suggested as possible methods for the creation of the analyte ions. In this work the existence of neutral hydrogen atoms in the ablation plume is reported. These are selectively ionized from the ground state through a (2+1) multiphoton resonant excitation scheme. The mass spectra at different delay times between the ablation and the post-ablation-ionization lasers have demonstrated the existence of hydrogen atoms with high velocities in the ablated plume.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 761-766 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A tandem reflectron time-of-flight mass spectrometer has been constructed for the investigation of laser photofragmentation of selected molecular ions. Ions are generated by an ablation laser and attracted by ion optics into the field-free flight region of a reflectron time-of-flight mass spectrometer. Laser photofragmentation of selected molecular ions takes place at the turn-around point of ions in the reflectron. Fragmentation mass calibration, parent ion selection, ion collection effects, reflectron field effects and the mass resolution of this tandem reflectron time-of-flight mass spectrometer are described. Furthermore it is shown that laser parameters may be used to control the fragmentation pattern.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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