ISSN:
0887-624X
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The hydrolysis and reactions of alkoxy silane groups have been studied on a model compound (TA) prepared from 2 mol of phenyl glycidyl ether and 1 mol of aminopropyl triethoxy silane. At low (40°C) and high (140°C) temperatures, the monomer conversion and the evolution of the molecular mass are followed by size exclusion chromatography (SEC). During the same reaction time, the evolution of the functional groups, hydroxyl CH—OH, ethoxy —O—C2H5, and siloxane Si—O—Si, is observed by FTIR spectroscopy. Without the presence of water, reactions between hydroxyl and ethoxy silane lead to gelation at the end of the reaction. A by-product, probably a cyclic tetramer is also formed. After the hydrolysis, the reaction of the model compound is quite different. The product of reaction is always soluble, even after a treatment at high temperatures, and the evolution of the molecular mass versus the reaction time seems to correspond to the condensation giving a dead cyclic tetramer. From this study it is evident that the curing cycle has a great influence on the properties of the interface of a composite based on a epoxy matrix.
Zusätzliches Material:
10 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pola.1991.080290806
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