ISSN:
1573-1561
Schlagwort(e):
Trogoderma species
;
trogodermal
;
enantiomers
;
chiral center
;
geometric isomers
;
methyl branching
;
(Z)- or (E)-14-methyl-8-hexadecenal
;
dermestid beetles
;
Coleoptera
;
Dermestidae
;
pheromone
;
chemoreception
;
olfaction
;
(Z)-hexadecenal
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Biologie
,
Chemie und Pharmazie
Notizen:
Abstract Responses to enantiomers of (Z)- and (E)-trogodermal (14-methyl-8-hexadecenal) suggest that fourTrogoderma species utilize the (R)-(−) configuration at C-14. Removal of the C-14 methyl branch decreased the response. These results demonstrate the high specificity associated with the configuration at a chiral center, or the methyl branch, distant in terms of numbers of bonds from a functional group.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00990475
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