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  • 1
    Electronic Resource
    Electronic Resource
    Reactions of trichloro(cyclopentadienyl)titanium(IV) with 1,5-diarylthiocarbazones (1987)
    Springer
    Transition metal chemistry 12 (1987), S. 335-338 
    Details
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The synthesis and characterization of the complexes from the reactions of trichloro(cyclopentadienyl)titanium(IV) with 1,5-diarylthiocarbazones (aryl=phenyl,o-tolyl,o-chlorophenyl,p-tolyl,p-chlorophenyl, or 3,5-dimethylphenyl) are reported. They are of the types CpTi(HDz)Cl2 and CpTi(HDz)2Cl (Cp=cyclopentadienyl, HDz−=the mono-anion of a 1,5-diarylthiocarbazone, H2Dz). The compounds are nonelectrolytes in dimethylformamide (DMF). In solid state, the far i.r. spectra of CpTi(HDz)Cl2 indicate the complexes to be dimeric, involving Cl-bridges.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01024027
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Preparation and characterization of bis(methylcyclopentadienyl)titanium(IV) dithizonate complexes (1986)
    Springer
    Transition metal chemistry 11 (1986), S. 321-323 
    Details
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Dichlorobis(methylcyclopentadienyl)titanium(IV) reacts with 1,5-diarylthiocarbazones (aryl=phenyl,p-tolyl,o-chlorophenyl orp-chlorophenyl) in 1∶1 and 1∶2 molar ratios in tetrahydrofuran in the presence of triethylamine, to yield [(MeCp)2Ti(HDz)Cl], [(MeCp)2Ti(Dz)] and [(MeCp)2-Ti(HDz)2] (MeCp=methylcyclopentadienyl; HDz− and Dz2− are the mono- and di-anions of a 1,5-diarylthiocarbazone, H2Dz).S-Methyl-1,5-diphenylthiocarbazone and [(MeCp)2TiCl2] react to give [(MeCp)2Ti(MeDz)Cl] and [(MeCp)2Ti(MeDz)2] (MeDz− represents the mono-anion ofS-methyl-1,5-diphenylthiocarbazone, HMeDz) in an excess of triethylamine. These new derivatives have been characterised on the basis of elemental analyses, magnetic moment, electrical conductance, i.r.,1H n.m.r. and electronic spectral studies.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00621513
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Reactions of dichlorobis(cyclopentadienyl)titanium (IV) with multidentate Schiff bases (1978)
    Springer
    Transition metal chemistry 3 (1978), S. 282-285 
    Details
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Dichlorobis(cyclopentadienyl)titanium(IV), Cp2TiCI2, reacts with bidentate Schiff bases such as salicylideneaniline, salicylidene-o-toluidine, salicylidene-m-toluidine, salicylidene-p-toluidine and 2-hydroxy-l-naphthyl
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01393569
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Preparation and characterization of bis(cyclopentadienyl)zirconium (IV) oximate complexes (1978)
    Springer
    Transition metal chemistry 3 (1978), S. 211-214 
    Details
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Oximate complexes of bis(cyclopentadienyl)zirconium(IV) chloride (Cp2ZrCl2 ) having the general formulae Cp2Zr(Ox), Cp2Zr(OxH)Cl and Cp2Zr(OxH)2 [where OxH2 = RC6H4C(OH)R′: NOH, R = H, Me, R′= H, Me, Et, n-Pr; PhC: N(OH)CH(OH)Ph and R″C : N(OH)N(OH): CR″, R″ = H, Me and Ph] have been synthesized by reacting bis(cyclopentadienyl)zirconium(IV) chloride with the appropriate oxime in tetrahydrofuran in the presence of triethylamine at room temperature. The complexes have been characterized by their elemental analysis, i.r. and electronic spectra, molecular weight determination, electrical conductance and magnetic measurements.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01393548
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    Paper (German National Licenses)
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