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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 114 (1992), S. 6580-6582 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 56 (1991), S. 2024-2030 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1572-8862
    Keywords: Rhodium carbonyl clusters ; rhodium-cobalt carbonyl clusters ; homogeneous catalysis ; hydrosilylation ; silylformylation ; silylcarbocyclization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The reactions of hydrosilane and/or alkyne as well as isonitriles with rhodium and rhodium cobalt mixed metal carbonyl clusters, e.g., Rh4(CO)12 and Co2Rh2(CO)12, are studied. Novel mixed metal complexes, e.g., CoRh(CO)5 (HC≡CBu n ), (R3Si)2Rh(CO) n Co(CO)4, Rh(R−N≡C)4Co(CO)4, Co2Rh2(CO)10(HC≡CR), and Co2Rh2(CO)9(HC≡CBu n ), are synthesized and identified. The catalytic activities of these rhodium and rhodium-cobalt mixed metal complexes are examined in hydrosilyation, silylformylation, and novel silylcarbocyclization reactions. Possible mechanisms for these reactions are proposed and discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 427-438 
    ISSN: 0271-2091
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The problem under investigation is that of fluid flow within an enclosed rectangular cavity. It is assumed that one wall is maintained at a constant temperature T1 (hot wall) and the other wall is maintained at a constant temperature T0 (cold wall). At the remaining walls, two separate cases are studied. In the first, an adiabatic boundary condition is assumed. That is, the normal derivative of the temperature function is assumed to be 0. In the second, it is assumed the temperature varies linearly from T0 to T1.The purpose of this paper is the application of a second order numerical technique to the problem of fluid flow within a heated closed cavity. The method is a modification of a method developed by Shay1 and applied to the driven cavity problem. In order to test the viability of this technique, it was decided to extend the technique to the problem of natural convection in a square. Jones2 proposed that this problem is suitable for testing techniques that may be applied to a wide range of practical problems such as reactor insulation, cooling of radioactive waste containers, solar energy collection and others.3The technique makes use of second-order finite difference approximations to all derivatives in the governing equations. Furthermore, second-order approximations are also used to determine boundary vorticities and, when the adiabatic boundary condition is used, for the boundary temperatures as well. In some works, where second-order approximations are used at interior points, second-order boundary approximations have been sacrificed in favour of a more stable, but first-order boundary approximation.The current approximations are generated by writing the unknown value of a function at a given interior node as a linear combination of unknown function values at all of the neighbouring nodes. Then the function values at these neighbouring nodes are expanded in a Taylor series about the given node. Through appropriate regrouping of terms and the use of the equations to the solved, constraints are imposed on the coefficients of the linear combination to yield a second-order approximation. As it turns out, there are more unknowns than constraints and, as a result, we are left with some freedom in choosing coefficients. In this work this freedom was used to choose coefficients in such a way as to maximize stability of the resulting system of equations. In other words, the approximations to the governing partial differential equation are individually determined at each point dependent on the direction of flow in order to generate the best possible stability. This idea is analogous to that used in the derivation of the upwind method. However, the current method is second-order accurate where the upwind method is only first-order accurate. Thus, what is generated is an easily implemented second-order method that yields a system of equations that has proved easy to solve.The system of equations is solved via the method of successive overrelaxation. The stability of the method is shown in the convergence for a wide range of Rayleigh numbers, Prandtl numbers and mesh sizes. Level curves of the stream, vorticity and temperature functions are provided for Rayleigh numbers (Ra) as large as 100,000, Prandtl numbers (Pr) as small as 0.0001, and mesh sizes as small as 0.0125. Values of the Nusselt number have also been calculated through the use of Simpson's rule, and a second order approximation to the normal derivative of the temperature along the cold wall. Comparisons are made with other current works to aid in the verification of this methods' accuracy and also with the first-order upwind method to demonstrate superiority over the first-order method.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 9 (1989), S. 1099-1111 
    ISSN: 0271-2091
    Keywords: Navier-Stokes ; Finite differences ; Reynolds number ; Rotating concentric spheres ; Stream function ; Second order accuracy ; Vorticity function ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes a second-order method to calculate approximate solutions to flow of viscous incompressible fluid between rotating concentric spheres. The governing partial differential equations are presented in the stream-vorticity formulation and are written as a series of second-order equations. The technique employed makes use of second-order approximations for all terms in the governing equations and is dependent upon the direction of flow at a given point. This upwind technique has allowed us to generate approximate solutions with larger Reynolds numbers than has generally been possible for second and higher-order techniques. Solutions have been obtained with Reynolds numbers as large as 3000 and with grids as fine as a 40 × 40 mesh. Results are displayed in the form of level curves for both the stream and vorticity functions. A dimensionless quantity related to the torque acting on both spheres has been calculated from the approximate solution and compared with other results. Results with smaller Reynolds numbers such as 100 and 1000 are in excellent agreement with other published results.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Experimental mechanics 30 (1990), S. 158-163 
    ISSN: 1741-2765
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The zero shifts of nickel-chromium foil strain gages (modified Karma) were measured over a period of three years at a constant temperature of 150°C in air. Three gage lengths were included—1.585 mm (1/16 in.), 3.170 mm (1/8 in.), and 6.340 mm (1/4 in.). The strain gages were bonded to constant-stress cantilever beams which were subjected to nomial mechanical strain levels of 0, ±780 μm/m, and ± 1350 μm/m. Each strian gage was connected by threewire leads to a Wheatstone-bridge circuit for the test duration. The data support two general observations: (1) short gage lengths suffer larger zero shifts than longer gage lengths, and (2) gages in compression suffer large zero shifts than gages in tension. On the assumption that the major cause of the zero shifts is a combination of corrosion of the foil and creep of the gage/epoxy/beam system, the author suggests a possible way to correct for the zero shift by experimentally determining the combined corrosion/creep effect and substracting it from the strain-gage readings. Some of the data appear to be consistent with this assumption, but some of the data do not.
    Type of Medium: Electronic Resource
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