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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 26 (1996), S. 90-94 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The composition, properties, structure and morphology of Zn-Fe alloy deposits obtained from an alkaline sulphate bath have been investigated. The bath containing triethanolamine produced smooth, uniform and bright Zn-Fe alloy deposits having the desired 15–25% Fe. The deposition potentials of Zn-Fe alloy lie between the potentials of the individual metals. Increased current density lowered the Fe percentage in the alloy deposit. The structure and morphology of the alloy deposits were found to depend on the Fe percentage in the alloy.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 67 (1999), S. 35-41 
    ISSN: 1588-2837
    Keywords: Kinetics of oxidation ; diazepam ; 1-chlorobenzotriazole
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The kinetics of oxidation of diazepam (DZ) by 1-chlorobenzotriazole (CBT) has been studied in HClO4 medium in the temperature range of 293–323 K. The reactions followed a first order dependence on [CBT], fractional order each in [H+] and [DZ]. Activation parameters were evaluated. A negative entropy of activation indicated the involvement of a rigid complex in the activated state. Variation of reaction rate with dielectric constant and the ionic strength are consistent with a mechanism involving the decomposition of a dipole in the rate-determining step. Rate equation is derived to account for the observed kinetic data and the proposed reaction mechanism.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Zinc electrodeposited from a sulphate bath on to copper single crystal planes revealed a layer-type growth on copper (111) and (100) planes and ridge-type growth on the (110) plane at low d.c. densities. Dendritic growth appeared at higher d.c. densities on all the planes. Superimposition of a.c. on d.c. during electrocrystallization produced hexagonal pyramids on the copper (111) plane, which were transformed into hexagonal dendrites under suitable a.c. to d.c. ratios. The influence of a.c. on the degree of epitaxy of zinc on copper and the mechanism of the dendrite initiation are discussed.
    Type of Medium: Electronic Resource
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