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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 46 (1996), S. 1511-1525 
    ISSN: 1572-8943
    Schlagwort(e): characterization ; epoxy ; extended cure time
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Five epoxy resins of different chemistry and functionality were cured with DDS (4,4′-diaminodiphenyl sulfone) using 2, 8 and 14 h curecycles. Both Differential Scanning Calorimetry (DSC) and Thermomechanical Analysis (TMA) were used to characterize reaction behavior and cured properties of the resin systems. In addition, static mechanical tests and density measurements were integrated with the thermal characterization methods to correlate resin properties with process time. Flexural three-point bending experiments showed that the resins tended to have higher yield stress and toughness values at extended cure times. The improved mechanical properties could be attributed to the full development of the epoxy molecular structure, in the form of cross-linked networks and molecular rearrangement. These results suggest that extended cure times or high temperature post-curing may be required to obtain the resin's ultimate mechanical properties for high performance composites.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 15 (1994), S. 453-463 
    ISSN: 0272-8397
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: The resin film infusion process (RFIP), which is similar to resin transfer molding (RTM), was applied to investigate the possibility of manufacturing high performance stitched composites. With the objective of understanding the resin flow mechanisms and void formation in stitched fibrous perform, two recent technological developments in homogeneous tough resin and bendable stitching fibers were incorporated in producing stituched composites with RFIP. These included new lightly crosslinked thermosets (LXT) that were phenolic or amine based. Second, bendable carbon stitching reinforcement (T-900) was utilized as a stitching fiber. Flow characteristics were inferred by ultrasonic C-scan analysis of cured panels. Microscopic studies indicated that voids were distrubuted along the stitching fiber because of low consolidation pressure in the resin-rich area (stitching fiber region) where the fiber volume content was lower. In contrast to stitched composites, non-sitiched composites contained lower void content and irregular void distribution because of uniform fiber compaction. Microscopic studies of partially resin infused quasi-istropic stitched composites demonstrated that the resin flows along the stitching fiber region and then infuses into the fibrous preform. These infusion phebnomena were the result of anistropic permeability in the preform. Consequently, anisotropic resin flow in the stitched fibrous preform was found to be related to the heterogenous textile structure caused by the stitching process.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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