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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemical reviews 48 (1948), S. 153-224 
    ISSN: 1520-6890
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 67 (1957), S. 0 
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 60 (1956), S. 813-815 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 61 (1957), S. 849-856 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 57 (1953), S. 396-403 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-9613
    Keywords: Stochastic processes ; nonlinear processes ; statistical linearization ; perturbation expansions ; projection operators
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We compare the methods of statistical linearization, perturbation expansions, and projection operators for the approximate solution of nonlinear multimode stochastic equations. The model equations we choose for this comparison are coupled, nonlinear, first-order, one-dimensional complex mode rate equations. We show that the method of statistical linearization is completely equivalent to the neglect of certain well-defined diagrams in the perturbation expansion resulting in the first Kraichnan-Wyld approximation, and to the retention of only Markovian terms in the projection operator method, i.e., those terms that are local in time.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 3 (1971), S. 365-379 
    ISSN: 1572-9613
    Keywords: Decay of correlations ; master equations, stochastic processes ; Ursell functions ; reduced distribution functions ; reduced master equations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We considerN-particle systems whose probability distributions obey the master equation. For these systems, we derive the necessary and sufficient conditions under which the reducedn-particle (n〈N) probabilities also obey master equations and under which the Ursell functions decay to their equilibrium values faster than the probability distributions. These conditions impose restrictions on the form of the transition rate matrix and thus on the form of its eigenfunctions. We first consider systems in which the eigenfunctions of theN-particle transition rate matrix are completely factorized and demonstrate that for such systems, the reduced probabilities obey master equations and the Ursell functions decay rapidly if certain additional conditions are imposed. As an example of such a system, we discuss a random walk ofN pairwise interacting walkers. We then demonstrate that for systems whoseN-particle transition matrix can be written as a sum of one-particle, two-particle, etc. contributions, and for which the reduced probabilities obey master equations, the reduced master equations become, in the thermodynamic limit, those for independent particles, which have been discussed by us previously. As an example of suchN-particle systems, we discuss the relaxation of a gas of interacting harmonic oscillators.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1572-9613
    Keywords: Ising lattice ; spin correlations ; spin distribution function ; dynamics of correlations ; master equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We have studied the relaxation of then-spin correlation function 〈σ (n)〉 and distribution functionP n(σ (n);t) for the Glauber model of the one-dimensional Ising lattice. We find that new combinations of correlation functions (C-functions) and distribution functions (Q-functions) are more useful in discussing the relaxation of this system from initial nonequilibrium states than the usual cumulants and Ursell functions used in our papers I and II. The asymptotic behavior of theP, C, andQ functions are:P n(σ (n);t) —P n (o) ∼P 1(σ;t) —P 1 (o) (σ);C n(σ (n); t) —C n (o) (σ (n)) ∼ 〈σ〉;Q n(σ (n)); —Q n (o) (σ (n)) ∼ [P 1(σ;t) —P 1 (o) (σ)]n; where the superscript zero denotes the equilibrium function. These results imply thatP n(σ (n);),n〉 2, decays to a functional of lower-order distribution functions as [P 1(σ;) —P 1 (o) (σ)]n and that then-spin correlation function 〈o(n)〉 withn 〉 2 decays to a functional of lower-order correlation functions as 〈σ〉n. This result for the distribution functionP n(σ (n);),n〉 2, is identical with the results obtained in papers I and II for initially correlated, noninteracting many-particle systems in contact with a heat bath and for an infinite chain of coupled harmonic oscillators. As a special example, we study the relaxation of the spin system when the heat-bath temperature is changed suddenly from an initial temperatureT o to a final temperatureT. We obtain the interesting result that the spin system is not canonically invariant, i.e., it cannot be characterized by a time-dependent “spin temperature.”
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 21 (1979), S. 517-548 
    ISSN: 1572-9613
    Keywords: Random walks ; periodic lattices ; random lattices ; generating function techniques
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We investigate the random walk properties of a class of two-dimensional lattices with two different types of columns and discuss the dependence of the properties on the densities and detailed arrangements of the columns. We show that the row and column components of the mean square displacement are asymptotically independent of the details of the arrangement of columns. We reach the same conclusion for some other random walk properties (return to the origin and number of distinct sites visited) for various periodic arrangements of a given relative density of the two types of columns. We also derive exact asymptotic results for the occupation probabilities of the two types of distinct sites on our lattices which validate the basic conjecture on bond and step ratios made in the preceding paper in this series.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 31 (1983), S. 255-278 
    ISSN: 1572-9613
    Keywords: Diffusion ; order statistics ; mean first passage times ; mean trapping times
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We consider the problem of the first passage times for absorption (trapping) of the firstj (j = 1,2, ....) ofk, j 〈k, identical and independent diffusing particles for the asymptotic case k≫〉1. Our results are a special case of the theory of order statistics. We show that in one dimension the mean time to absorption at a boundary for the first ofk diffusing particles, μ1,k , goes as (lnk)−1 for the set of initial conditions in which none of thek particles is located at a boundary and goes ask −2 for the set of initial conditions in which some of thek particles may be located at the boundary. We demonstrate that in one dimension our asymptotic results (k21) are independent of the potential field in which the diffusion takes place for a wide class of potentials. We conjecture that our results are independent of dimension and produce some evidence supporting this conjecture. We conclude with a discussion of the possible import of these results on diffusion-controlled rate processes.
    Type of Medium: Electronic Resource
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