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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 66 (1994), S. 2640-2646 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 2 (1964), S. 334-354 
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Résumé La capacitance et l’angle des pertes de quelques phosphores sont mesurés en fonction de l’intensité d’irradiation à différentes températures et à différentes fréquences. La décroissance de l’effet photocapacitif après disjonction de l’irradiation est observée. Des critères sont développés pour discerner les effets photoconductif de première espèce (dû aux électrons en bande de conductivité), photoconductif de seconde espèce (dû aux électrons dans une bande d’impurité) et photodiélectrique (dû aux électrons en pièges). Ils sont fondés à la décroissance à température basse (vite; lente; lente) et à la dispersion aux fréquences basses (forte; forte; faible). L’équilibre entre les électrons en bande de conductivité et en pièges est essentiel même pour l’effet photoconductif de première espèce. Il est néanmoins possible de déterminer la conductivité des mesures de la capacitance.
    Abstract: Abstract Capacitance and loss angle of several phosphors are measured as a function of exciting irradiation intensity at different temperatures and different frequencies. Furthermore, the decay of the photocapacitive effect after shutting off the radiation is observed. Criteria are developed for deciding whether the photocapacitive effect is due to conduction band electrons (photoconductive effect of first kind), to impurity band electrons (photoconductive effect of second kind), or to polarization of filled traps (photodielectric effect). These are based on the decay behavior at low temperature (fast, slow, slow, respectively) and the dispersion at low frequencies (strong, strong, weak, respectively). It is shown that even for the photoconductive effect of first kind the interplay of conduction band and shallow traps is essential but that, nevertheless, conductivity data can be obtained from capacitance measurements.
    Notes: Zusammenfassung Kapazität und Verlustwinkel einiger Phosphore werden als Funktion der Bestrahlungs-instensität bei verschiedenen Temperaturen und Meßfrequenzen gemessen. Ferner wird das Abklingen des photokapazitiven Effekts nach Abschalten der Strahlung beobachtet. Es werden Kriterien entwickelt zur Entscheidung der Frage, ob der photokapazitive Effekt Leitungselektronen zugeschrieben werden kann (Photoleitungseffekt 1. Art), Störband-Elektronen (Photoleitungseffekt 2. Art) oder der Polarisation gefüllter Haftstellen (photodielektrischer Effekt). Diese beruhen auf dem Abklingungsverhalten bei niedriger Temperatur (schnell, bzw. langsam, bzw. langsam) und der Dispersion im Niederfrequenzgebiet (stark, bzw. stark, bzw. schwach). Selbst für Photoleitungseffekt 1. Art ist der Beitrag von Elektronen in flachen Haftstellen wesentlich; die Leitfähigkeit kann aber trotzdem aus Kapazitätsmessungen bestimmt werden.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 189-193 
    ISSN: 1434-1948
    Keywords: Mixed-valent compounds ; Nickel ; N2Se ligand ; Cyclic voltammetry ; EPR spectroscopy ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two dinuclear nickel amine-selenolate complexes of the tridentate amine-selenolate ligand, 4-tert-butyl-2,6-di(aminomethyl)selenophenol (1b), have been synthesized and their properties characterized. The green complex [NiII2(1b)3]Cl (4a) is readily prepared from 1b, NiCl2 · 6 H2O, and NaOMe in methanol or by reaction of coordinatively unsaturated [NiII2(1b)2][BPh4]2 (2b) with another one equivalent of 1b in the presence of triethylamine. The face-sharing, bioctahedral structure of 4a is derived from UV/Vis spectroscopy, cyclic voltammetry, and single-crystal X-ray diffraction of its oxidation product, [NiIINiIII(1b)3]2+. The dication was prepared by air-oxidation of 4a in MeOH and isolated as the dark-brown BPh4- salt, [NiIINiIII(1b)3][BPh4]2 · CH3OH (4b). Mixed-valent complex 4b consists of a dinuclear, face-sharing bioctahedral dication with a central N3NiII(μ2-SeR)3NiIIIN3 core and well-separated tetraphenylborate anions. Distortions from D3h symmetry suggest that 4b is a trapped-valence compound in the solid-state. On the CV time scale complex 4a undergoes two reversible one-electron oxidations at E11/2 = -0.15 and at E21/2 = +0.29 V vs SCE, affording 4b and the thermally not stable trication [NiIII2(1b)3]3+, respectively. The EPR spectrum of a powdered sample of 4b reveals an S = 3/2 ground state of the mixed-valent NiIINiIII complex.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 90 (1978), S. 148-148 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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