ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The square-planar RhI complex, [Rh(trop)(PFcPh2)(CO)] (tropH = 2-hydroxy-2,4,6-cycloheptatrienone, C7H6O2, and PFcPh2 = ferrocenyldiphenylphosphine, C22H19FeP), contains a five-membered chelate ring. The most important bond lengths and angles include Rh—O 2.0838 (14) Å (trans to P) and Rh—O 2.0487 (14) Å (trans to CO), Rh—P 2.2395 (5) Å, Rh—C 1.803 (2) Å, and O—Rh—O 77.56 (6)° and P—Rh—C 89.73 (7)°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801011448
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