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  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Three acrylate monomers having mesogenic moieties based on 4-(n)-alkyloxy-4′-(2-chloro-propanoyloxy)biphenyl (n = 6, 8 or 10) have been synthesized. There is no evidence for liquid-crystal properties in any of the three new monomers. The corresponding polymers have been prepared by free-radical polymerization. Their liquid-crystal behavior has been investigated by differential scanning calorimetry, polarized optical microscopy, and X-ray diffraction. On cooling from the isotropic liquid, smectic A (SA), smectic B (SB) and crystalline phases (probably crystal-like SE phases) have been evidenced. It should be noted that the chlorine atoms in the chiral groups do impose a local ordering of the mesogenic side groups.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Acrylate monomers with a chiral group have been synthesized bearing a propyl, isopropyl or benzyl substituent on the asymmetric carbon. All of the monomers are crystalline. Above their melting point, they give a clear, isotropic melt. The corresponding polymers have been prepared by free radical polymerization. They were examined by differential scanning calorimetry, optical microscopy and X-ray diffraction. They were found to show a reproducible liquid-crystal behavior. On cooling from the isotropic state, SA, SF* (or SI*) and crystal-like (probably SH or SH′) phases become evident. Our results do not preclude the existence of a SC* phase between the SA and SF* phases. It is noteworthy that polyacrylates of the same series but with side chains terminated by a chiral group bearing a methyl substituent exhibit SA, SB and crystal-like (probably SE) phases.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 43 (1998), S. 433-440 
    ISSN: 0021-9304
    Keywords: NiTi shape memory alloy ; stents ; surface treatments ; corrosion resistance ; surface characterization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Because of its good radiopacity, superelasticity, and shape memory properties, nickel-titanium (NiTi) is a potential material for fabrication of stents because these properties can facilitate their implantation and precise positioning. However, in vitro studies of NiTi alloys report the dependence of alloy biocompatibility and corrosion behavior on surface conditions. Surface oxidation seems to be very promising for improving the corrosion resistance and biocompatibility of NiTi. In this work, we studied the effect on corrosion resistance and surface characteristics of electropolishing, heat treatment, and nitric acid passivation of NiTi stents. Characterization techniques such as potentiodynamic polarization tests, scanning electron microscopy, Auger electron spectroscopy, and X-ray photoelectron spectroscopy were used to relate corrosion behavior to surface characteristics and surface treatments. Results show that all of these surface treatments improve the corrosion resistance of the alloy. This improvement is attributed to the plastically deformed native oxide layer removal and replacement by a newly grown, more uniform one. The uniformity of the oxide layer, rather than its thickness and composition, seems to be the predominant factor to explain the corrosion resistance improvement. © 1998 John Wiley & Sons, Inc. J Biomed Mater Res (Appl Biomater) 43: 433-440, 1998
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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