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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 889-895 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization ability of two new pyrazolone-containing monomers - 3-methyl-1-phenyl-4-crotonoyl-pyrazolone-5 (Cr) and 3-methyl-1-phenyl-4-(3′-phenyl-acryloyl) pyrazolone-5 (Cy) - was investigated. The monomers were obtained by acylation of 3-methyl-1-phenyl-pyrazolone-5 with crotonyl chloride or cinnamoyl chloride, respectively. It was established that the two monomers do not homopolymerize either under the action of ionic and radical initiators nor with γ-rays (doses between 2 and 10 MRad). In contrast to this, the two monomers copolymerize with other vinyl comonomers. Copolymers of Cr and Cy with methacrylic acid (MAA), methyl methacrylate (MMA), and Styrene (St) were synthesized by radical copolymerization. The molecular weights of the polymer products obtained were in the 10,000-65,000 range. It was established that the molecular weight characteristics of the copolymers were affected by the concentration of the pyrazolone-containing monomer and by the chemical nature of the solvent used. The copolymerization of Cr and Cy with MAA was investigated in detail in order to evaluate the relative activity of the new monomers during copolymerization. The reactivity ratios (r) were calculated by three different methods with good agreement. The values obtained for the monomer pairs are: rMAA = 0.61 ± 0.01, rCr = 0.04 ± 0.01; rMAA = 0.64 ± 0.05, rCy = 0.02 ± 0.02. The Q/e values for Cr and Cy were determined using the reactivity ratios of both monomers.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 1631-1638 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Terpolymers of methyl methacrylate and methacrylic acid with vinyl monomers, styrene, 4-(α, α-dimethylbenzyl) phenyl methacrylate and 2-naphthyl methacrylate, were synthesized by radical terpolymerization. The molecular weights of the polymers obtained cover the range of 40,000 to 120,000. It was established that the molecular weight characteristics of the terpolymers are influenced by the content of methacrylic acid in the initial polymerization mixtures, by the chemical nature of the aromatic vinyl comonomer, and by the nature of the solvent and the concentration of the initiator. The sensitivity of the polymers towards radiation was estimated by the G-values obtained after the products were subjected to γ-ray treatment. The influence of the chemical composition of the terpolymers on their sensitivity is discussed in detail. © John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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