ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary [Au(SR)]6 (R = C6H2Me3-2,4,6 or C6H2Pr inf3 supi -2,4,6), prepared by treatment of chloroauric acid in water with thiodiglycol followed by reaction with the appropriate thiol (HSR) in CHCl3, can add PPh3 in CH2Cl2 to give [Au(SR)(PPh3)], which, alternatively, can be obtained from reaction of [AuCl(PPh3)] in THF with HSR in the presence of KOH-EtOH. The molecular structure of [Au(SC6H2Pr inf3 supi -2,4,6)(PPh3)] has been determined by X-ray diffraction analysis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00139133
Permalink