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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 384-390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown in a series of illustrative examples how the conversion efficiency of many reactions can be markedly affected by the type of reactor used, even though the temperatures, catalyst, and basic kinetics are already fixed by the chemistry of the process.For such purpose graphical and analytic criteria are developed which permit the selection of a continuous stirred tank or tubular reactor system to obtain the most advantageous conversion of raw material to desired product. When a continuous stirred tank reactor process is preferable, the optimum number of reactor stages for maximum conversion is one. An example is given of a case where a combination of a continuous stirred tank and a tubular reactor is advantageous.A new graphical method of reactor design for simple or complex reactions is also introduced. This method utilizes continuous stirred tank reactor data directly rather than batch data or kinetics analyses.Reactions are classified according to the kinetic and stoichiometric characteristics which determine the allowable design procedures and the differences in the compostions paths occurring in batch, tubular, or continuous stirred tank reactors.The mathematical analysis of continuous stirred tank reactor systems for complex reactions leads to a set of difference equations. For cases of zero- or first-order reactions these are readily solved as illustrated in examples, even when several independent components influence the reaction kinetics.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 574-578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The theory of extractive reaction is extended to concentrated solutions where the distribution coefficients are no longer constant and where important changes in phase volumes may occur. The methods developed are applicable to simple or complex reactions of any order. Two- and one-solvent systems are treated, and convenient graphical methods are developed and illustrated with numerical examples.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 394-400 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A reaction process occurring simultaneously with an extraction by an immiscible phase is referred to herein as extractive reaction.Quantitative relations are developed which show how the rate of reaction, volumetric efficiency, and reactant conversion of a single-phase batch reaction can be enhanced by deliberately adding to the batch a second phase such as an immiscible solvent or an inert gas.Analytical solutions are also obtained for continuous-flow extractive reactions of first order and of simple or complex stoichiometry occurring in single- or multistage stirred-tank reactors. The effect of recirculated or side streams is included.Dilute systems and several types of reactions are considered. The equations are applicable, for instance, to liquid-liquid systems and solid-liquid or gas-liquid processes wherein reaction occurs in either the vapor or condensed phase.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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