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Mass spectra of some labda-7,14-dien-13(R)-ol monoglycosides under electron impact (1983)

Eguchi, Shizuko ; Uchio, Yasuto ; Nakayama, Mitsuru

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 10 (1983), S. 363-368

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ISSN: 0306-042X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The mass spectral fragmentation behaviour of some labda-7,14-dien-13(R)-ol monoglycosides has been studied. Mass spectra of O-isopropylidine derivatives of the glycosides have been determined to distinguish the isomeric sugar moieties containing rhamnopyranose, fucopyranose and 6-deoxyidopyranose, respectively. The main fragment ions of the sugar moieties were investigated with the aid of deuterium labelling and high resolution mass measurement.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bms.1200100605

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