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A New Route to Iminoarsanes (2000)

Kruppa, Christian ; Nieger, Martin ; Ross, Bernd ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 165-168

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ISSN: 1434-1948

Keywords: Arsenic ; Imino compound ; Hydrazinoiminoarsane ; Aminoiminoarsane ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Dehydrohalogenation of (2,4,6-tri-tert-butylphenylamino)chloro[tris(trimethylsilyl)hydrazino]arsane (3) or [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane (4) with DBU yields novel stable compounds containing an As-N double bond, (2,4,6-tri-tert-butylphenylimino)[tris(trimethylsilylhydrazino]arsane) (5) and [tert-butyl(trimethylsilyl)amino](2,4,6-tri-tert-butylphenylimino)arsane (6). The structure of 5 was confirmed by an X-ray structure determination.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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