ISSN:
0044-2313
Keywords:
Fullerene C60, C70
;
Crystallization from non-polar solvents
;
Characterization of co-crystals
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Characterization of the Fullerene Co-Crystals C60 · 12 C6H12, C70 · 12 C6H12, C60 · 12 CCl4, C60 · 2CHBr3, C60 · 2CHCl3, C60 · 2H2CCl2By crystallization of fullerenes from non-polar solvents (C6H12, CCl4, CHBr3, CHCl3, H2CCl2) compounds of the following compositions were obtained: C60 · 12C6H12, C70 · 12C6H12, C60 · 12CCl4, C60 · 2CHCl3, C60 · 2CHBr3 and C60 · 2H2CCl2.Lattice parameters have been determined by X-ray diffraction of powder samples; according to single-crystal examinations on C60 · 12C6H12, C60 · 12CCl4 and C60 · 2CHBr3 the fullerene is orientationally disordered.C60 · 12C6H12, cubic, a = 28.167(1) Å; C70 · 12C6H12, cubic, a = 28.608(2) Å; C60 · 12CCl4, cubic, a = 27.42(1) Å; C60 · 2CHBr3, hexagonal, a = 10.212(1), c = 10.209(1) Å; C60 · 2CHCl3, hexagonal, a = 10.08(1), c = 10.11(2) Å; C60 · 2H2CCl2, tetragonal, a = 16.400(1) Å, c = 11.645(7) Å.
Notes:
Bei der Kristallisation von Fullerenen aus unpolaren Lösungsmitteln (C6H12, CCl4, CHBr3, CHCl3, H2CCl2) entstehen Kokristallisate der Zusammensetzung C60 · 12C6H12, C70 · 12C6H12, C60 · 12 CCl4, C60 · 2CHCl3, C60 · 2CHBr3 und C60 · 2H2CCl2. Die Gitterparameter wurden durch Röntgenbeugung an Pulvern bestimmt, nach Einkristalluntersuchungen an C60 · 12C6H12, C60 · 12CCl4 und C60 · 2CHBr3 liegt Orientierungsfehlordnung von C60 vor.C60 · 12C6H12, kubisch, a = 28,167(1) Å; C70 · 12C6H12, kubisch, a = 28,608(2) Å; C60 · 12CCl4, kubisch, a = 27,42(1) Å; C60 · 2CHBr3, hexagonal, a = 10,212(1), c = 10,209(1) Å; C60 · 2CHCl3, hexagonal, a = 10,08(1), c = 10,11(2) Å; C60 · 2H2CCl2, tetragonal, a = 16,400(1) Å, c = 11,645(7) Å.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210105
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