ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
1.2-Dithia-cyclopentenes, XVII1) Substitution on the 1.2-Dithia-cyclopenteneimine System5-Chloro- and 5-tosyl-1.2-dithia-cyclopenteneimines (1-5, 12, 14, 19, 20) react with nucleophilic compounds in 5-position. 4 and thiourea yield the 1.2-dithiol-3-thione 24, which is alkylated at the thione group. Alkaline cleavage of 10r yields the thiophenes 37, 38, or 39.
Notes:
5-Chlor- und 5-Tosyl-1,2-dithia-cyclopentenimine (1-5, 12, 14, 19, 20) reagieren mit nucleophilen Partnern in 5-Stellung zu den Substitutionsprodukten. 4 liefert mit Thioharnstoff das Trithion 24, das am Thion-Schwefel alkyliert wird. Alkalische Spaltung von 10r führt zum Thiophen-System (37-39).
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.19707340117
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