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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 6870-6883 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A formalism for designing an optical field for selective vibrational excitation in linear harmonic chain molecules is presented based on optimal control theory. The optimizing functional producing the field designs is flexible to allow for the imposition of desirable laboratory and theoretical constraints. The designed optimal fields, which successfully lead to local bond excitations, exhibit complex structure on the time scale of 10 fs. Analysis of the optimal fields shows a high degree of cooperativety between the temporal structure of the fields and the dynamical capabilities of the molecules. It is generally impossible using only spectral information to devise the optical field needed to selectively excite a local bond in a polyatomic molecule. These results explain why the previous intuitively based laboratory attempts at site specific chemistry have yielded disappointing results.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Science & education 3 (1994), S. 215-244 
    ISSN: 1573-1901
    Source: Springer Online Journal Archives 1860-2000
    Topics: Natural Sciences in General
    Notes: Abstract In 1590, or thereabouts, Galileo wrote the manuscript De Motu (Galileo 1590). In this text he attempted to demonstrate the errors of Aristotelian natural philosophy and began his lifelong attempt to construct a science of motion. The chief device in De Motu was his wide ranging use of the balance. The balance was a simple machine, familiar to all, that Galileo could describe using principles of equilibrium. In this paper we suggest an empirical thesis: Galileo understood something important when he used the balance as the basic equilibrium model in order to understand all the phenomena of motion. Galileo used the balance model to make intelligible problems of dynamics as well as kinematics (as we anachronistically call them). We believe that using the Galilean balance equilibrium model today in physics classes at the secondary and college levels (and probably even at the elementary school level) would provide students with a model of intelligibility that would unify their thinking about motion and, at the same time, provide them with a general procedural schema for solving motion problems.
    Type of Medium: Electronic Resource
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