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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 1223-1229 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Iodine-doped ZnSe films have been grown on GaAs by low-pressure metalorganic vapor-phase epitaxy using dimethylzinc and hydrogen selenide as reactants. In order to accomplish an accurate control of the carrier concentration in the films over a wide range, ethyliodide diluted to 1000 ppm was used as a dopant source. It has been shown that the carrier concentration can be changed in the range from 1015 to 1019 cm−3 by varying the flow rate of ethyliodide. Furthermore, the films with carrier concentrations below 1018 cm−3 exhibit strong blue emission with suppressed deep level emissions. The origin of blue emission has been ascribed to the iodine donors incorporated during growth. According to the results shown, it has been concluded that iodine is a superior donor dopant for ZnSe from a standpoint of the controllability and reproducibility of electrical and photoluminescence properties of the n-type films over a wide range.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 3256-3258 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Reported discrepancy of phase separation in InxGa1−xN films between experimental studies and theoretical calculations based on the usual regular solution model is discussed from the standpoint of phase diagram. The inclusion of higher-order pairwise interactions in the theoretical model may allow the system to undergo a spinodal decomposition in an asymmetrical manner as revealed by experiments. It is suggested that basal-plane atomic ordering in the In-rich precipitates should accompany the decomposition. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 60 (1992), S. 1330-1332 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Quantitative characterization of disorder and strain in ZnSxSe1−x/GaAs lattice-mismatched semiconductor heterostructures was successfully done by means of Raman spectroscopy. The alloy disorder and the phonon coherence length in epitaxial ZnSxSe1−x films were estimated from the Raman linewidth of the ZnSe-like LO phonon by using a spatial correlation model. The strain due to the lattice mismatch near the interface between ZnSxSe1−x and GaAs was deduced from the linewidth of the GaAs LO phonon.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 1700-1702 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Higher order (up to the 5th order) zone-folded acoustic modes in ZnSe-ZnS strained-layer superlattices (SLSs) were observed by means of Raman scattering. Structural characterization of both periodicity of superlattices and roughness of the interface was done by means of transmission electron microscopy (TEM). The Raman spectrum of zone-folded modes was well explained by the theoretical calculation which takes account of two observed structural characteristics of the sample, the periodicity of the superlattices, and the roughness of the interface. This clearly shows the strain does not matter to the observation of the zone-folded modes.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-482X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract X-ray diffraction reciprocal space maps and pole figures were used to analyse the cubic GaN epitaxial layers grown on (0 0 1) GaAs by r.f. plasma source MBE; the presence of hexagonal phase in cubic GaN layers was detected by high resolution x-ray analysis and the relationships among various crystal axes of cubic and hexagonal phase GaN were analysed with respect to V/III source-supply ratio. As for the growth conditions of the epitaxial layers, the V/III ratio was found to drastically affect the quality of the layers. High-temperature growth under near-stoichiometric conditions was necessary to obtain high quality epitaxial layers. It was found that inclusion of the hexagonal phase in the cubic GaN layers could be less than 0.4%, though previously reported typical c-GaN epitaxial layers included as much as 10–20% hexagonal phase GaN. On the basis of the measurements and analyses of reciprocal space maps and pole figures, it was revealed that the orientation of crystal axes of the hexagonal phase was unique in the present GaN epitaxial layers and they were different from those of previously reported c-GaN epitaxial layers.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 19 (1998), S. 902-911 
    ISSN: 0192-8651
    Keywords: catalysis ; effective core potentials ; mercury chemistry ; methane activation ; quantum chemistry ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: A computational investigation of methane activation by HgII complexes is reported. Calculated geometries and energetics of Hg(II)-containing reactants and products are consistent with available experimental data for a wide range of diverse ligand types. Calculated reaction enthalpies and activation barriers for HgII complexes cover a wide range of values for different ligands. This diversity suggests that the kinetics and thermodynamics of methane activation by Hg(II) and related medium-valent complexes can be tailored through rational modification of the ligand environment. Calculated activation barriers and reaction enthalpies for methane activation by Hg(II) complexes indicates that harder, more electronegative, ligands are kinetically and thermodynamically preferred. Potential donor groups on the activating ligand can stabilize the transition state versus the ground state reactants and hence result in substantially lower methane activation barriers.   © 1998 John Wiley & Sons, Inc.   J Comput Chem 19: 902-911, 1998
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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