ISSN:
1572-8838
Keywords:
Electrocatalytic hydrogenation
;
Porous electrode model
;
Raney nickel
;
Soybean oil
;
Process design
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract The process flowsheet for a soybean oil electrohydrogenation plant has been devised and heat and mass balance calculations on unit operations equipment were performed using a commercially available process simulation software package (PRO/II from Simulation Sciences, Inc.). The design and anticipated performance (current efficiency and power requirements) of the electrochemical flow cells were based on a laboratory-scale radial-flow-through Raney nickel powder electrocatalytic hydrogenation reactor. A semiempirical porous electrode model, that reproduced laboratory-scale reactor data, was incorporated into the PRO/II software as a unit operations subroutine module. Operation of a 3.0×106kgy−1 electrochemical plant was simulated on a computer for different soybean oil/electrolyte feeds and reactor current densities. Based on the PRO/II results, an economic analysis of the process, including capital, installation and operating costs of all equipment was carried out. The lowest total production cost for a brush hydrogenation oil product (20% reduction in the number of double bonds) was obtained at a current density of 15mAcm−2 and a feed composition of 10wt:vol% soybean oil in solvent/supporting electrolyte (US0.13kg−1 for an assumed five year straight line depreciation of capital equipment). This cost was higher than that for a comparable-size chemical catalytic soybean oil hydrogenation plant (US0.019kg−1). When the cost of the soybean oil starting material (US0.68kg−1) was factored into the economic analysis, the production plus raw material cost of the electrocatalytic process was only 16% greater than that for the chemical catalytic plant. The production cost for the electrosynthesized hydro-oil product may be tolerable because the oil has a high nutritional value (a lower trans isomers content) which may command a higher selling price.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1018415532741
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