ISSN:
0009-2940
Keywords:
Oxidative coupling of cyclopentadienide anion
;
Dihydrofulvalene, molecular structure
;
Migration of trimethylsilyl group
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of 1,2,4-tris(trimethylsilyl)cyclopentadienyllithium with ferric chloride in THF at -95°C leads to the formation of a thermally sensitive iron(III) complex which decomposes to the new dihydrofulvalene derivative 3,7-dihydro-1,3,3,5,7,7-hexakis(trimethylsilyl)fulvalene (1).
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240716
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