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  • Artikel: DFG Deutsche Nationallizenzen  (2)
  • 1995-1999  (2)
Datenquelle
  • Artikel: DFG Deutsche Nationallizenzen  (2)
Materialart
Erscheinungszeitraum
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Oxidation of metals 43 (1995), S. 363-378 
    ISSN: 1573-4889
    Schlagwort(e): superalloys ; UHBA 25L ; Sanicro 28 ; Inconel 690 ; air oxidation ; reaction kinetics ; oxide-scale morphology
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract In continuation of previous work, the oxidation behavior of three more alloys, namely UHBA 25L, Sanicro 28, and Inconel 690, was studied at high temperatures (600 to 1200°C). The oxidation kinetics of UHBA 25L and Sanicro 28 followed the parabolic-rate law at 800 and 1000°C. At 600°C oxidation rates were very low, while at 1200° C the parabolic-rate law was initially observed, followed by “breakaway.” Both alloys suffered extensive spalling at all temperatures, despite their high Cr contents of about 25% and 27%, respectively. This is atrributed to significant amounts of Mn present. Sanicro 28, with higher Cr, suffered an early breakaway at 1200°C because of the presence of Mo, which forms a low-melting oxide. Inconel 690 showed mixed behavior at 600 and 800°C, parabolic at 1000°C and cubic at 1200°C. Inconel 690 and Incoloy 800H gave the best overall performance for the range of temperature and exposure time under study. This may be ascribed to the absence of Mo, the presence of small amounts of Ti and Al, and relatively small amount of Mn in these alloys.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of radioanalytical and nuclear chemistry 224 (1997), S. 3-6 
    ISSN: 1588-2780
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik
    Notizen: Abstract The Mössbauer technique has been used to study the oxidation of alloy 1.4306S (SS-304L) at 1200°C exposed in atmospheres of air and steam, for, 1, 6, 24, 100 and 400 hours. By oxidation in air the major products are α-FE2O3, γ-FE2O3, and Fe3O4 while, during oxidation in steam they are δ-FeOOH, γ-Fe2O3 and Fe3O4. A minor phase detected following both kinds of oxidation may be ascribed to MnCrFeO4, Cr2FeO4, δ-FeOOH and γ-FeOOH produced in steam only while the base material is found following air oxidation. The proportion of Fe3O4 on the scale remains constant for all exposure durations in air oxidation, while it becomes constant in steam oxidation only in cases where the entire sample has been oxidized.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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