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  • 1970-1974  (3)
  • 1970  (3)
Material
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  • 1970-1974  (3)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 240 (1970), S. 1-16 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Isomer shift (IS) and electric quadrupole splitting (QS) of the 77 keV γ-rays of Au197 were investigated for a large number of Au (I) and Au (III) compounds at 4.2 °K by nuclear γ-resonance Spectroscopy. A close correlation between the observed isomer shifts and the spectrochemical series of the ligands was observed. For each oxidation state, isomer shift and electric quadrupole splitting show approximately a linear relationship. On the basis of LCAO-MO theory, the experimental results are interpreted by covalency effects in the molecular orbitals, synergic coupling of σ- and π-bonds, and the empirically known donor and acceptor properties of the ligands.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 240 (1970), S. 100-122 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The magnetic hyperfine splitting of the 72.5 keV γ rays of145Nd was investigated in intermetallic compounds of Nd and in the paramagnetic salts Nd x Y 1-x Cl3·6H2O (withx=0.02 andx=0.05) at 4.2 K. With the magnetic hyperfine tensorA of Nd0.01Y0.99Cl3·6H2O known from EPR spectroscopy, the analysis of the unresolved magnetic hyperfine spectra yieldsI e =5/2 for the spin of the 72.5 keV state, in contradiction to a previous result. The multipolarity of the 72.5 keV γ transition was found to be essentiallyM1 with δ2=0.010±0.014, and the magnetic moment of the 72.5 keV state was determined as μ(5/2)=−0.319±0.004 nm. For various divalent and trivalent Nd compounds as well as for metallic Nd the isomer shift IS of the 72.5 keV γ line was measured. A value for the change of the mean square nuclear charge radius during the 72.5 keV γ transition of Δ〈r 2〉=+(1.9±0.9)·10−3fm2 was deduced using electron density differences from free-ion Hartree-Fock calculations.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 230 (1970), S. 80-88 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The spectroscopic quadrupole moments and the magnetic dipole moments of the lowest 2+ states in186Os (137 keV) and188Os (155 keV) have been determined by Mößbauer transmission experiments. The electric quadrupole momentsQ 2+(Os 186)=− (1.80±0.22) b andQ 2+(Os 188)=−(1.81±0.24) b as well as their ratioQ 2+(Os 188)/Q 2+(Os 186)=1.00±0.07 within the limits of error agree withB(E2) data, if a comparison on the basis of the rotational model is made. For the g-factors and their ratio g2+(Os 186)=0.281±0.008, g2+(Os 188)=0.305±0.015 andg 2+(Os 188)/g 2+(Os 186)=1.08±0.05 was obtained. All results are compared with recent model calculations.
    Type of Medium: Electronic Resource
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