ISSN:
0049-8246
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Physics
Notes:
The shift of the K-absorption edge (ΔEK) was measured in Se80-xTe20Inx, where 0 ≤ x ≤ 20. It is observed that the K-edge of Se shifts progressively towards the lower energy side as the In concentration increases from 0 to 15 at.-%. However, at higher concentrations, the relative shift starts to decrease. The results are in accordance with the Pauling concept of electronegativity and indicate that the nature of the bonds is iono-covalent in these glasses, as found in many crystalline solids. The composition dependence of the edge shift is also discussed in terms of the structure of the Se-Te system.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/xrs.1300190508
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