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Notes: The importance of dentofacial attractiveness to the psychosocial well-being of an individual has been well established. Very little information is available regarding dental patient perceptions of a pleasing esthetic image. The purpose of this study was to identify factors distinctive to attractive smiles versus unattractive smiles, as perceived by patients.〈section xml:id="abs1-2"〉〈title type="main"〉Materials and MethodsStandardized format photographs (5 × 7 in, matte finish, at f-32 and 1:2 magnification) of eight male and eight female smiles, framing only lips and teeth, were viewed by 297 subjects. The smiles exhibited differences in symmetry, tooth shade, number of teeth displayed, and height of maxillary lip line, and included both restored and unrestored teeth. Respondents ranked the photographs in order from most to least appealing appearance. Respondents viewed each series of photographs in a similar lighting and time period. A questionnaire identified the respondent's age, sex, race, education, income, and home town. Twenty-five demographic groups were established from the information in the questionnaire. Data were analyzed using stepwise discriminant analysis to determine the combination of smile characteristics that best predicted the ranking.〈section xml:id="abs1-3"〉〈title type="main"〉ResultsThe same female smile was chosen as the most attractive by 24 of the 25 demographic groups. This smile is characterized by natural teeth having light shade, high lip line, a large display of teeth, and radiating symmetry. Two female smiles typified by darker shade and asymmetry were rated by all groups as being least attractive. Two male smiles were judged equal as the most pleasing esthetically. Respondents favored those smiles characterized by light shade, a moderate display of teeth, moderate lip line, and a symmetrical arrangement of teeth. One male smile characterized by darker shade was rated as least attractive.〈section xml:id="abs1-4"〉〈title type="main"〉ConclusionsIn all cases, tooth shade was the most important factor, followed in sequence by unrestored natural teeth and number of teeth displayed. No correlation was found to exist between specific demographic groups and smile variables.

Notes: While the same atomic mechanism is usually assumed in both viscous flow and diffusion in a liquid, viscous flow is found much faster (by many orders of magnitude) in all situations studied where the mass transfer is caused by pressure gradients. A detailed study shows that Fick's law must be modified for self-diffusion in liquids. © 1996 American Institute of Physics.

Notes: Carbon-coated iron, cobalt, and nickel particles were produced by an arc discharge process modified in the geometry of the anode and the flow pattern of helium gas. Field emission scanning electron microscopy shows that the resulting material consists of only carbon-coated metal particles without any nanotubes or other unwanted carbon formations present. The diameters of iron, cobalt, and nickel particles range predominantly from 32 to 81 nm, 22 to 64 nm, and 16 to 51 nm, respectively. X-ray diffraction analysis confirmed that the as-made particles are carbon-coated elements rather than metal carbides. High resolution transmission electron microscopy reveals that the as-made cobalt and nickel particles are covered by 1–2 graphitic layers, while iron particles are surrounded by amorphous carbon. When the samples were treated by annealing or immersion into nitric acid, particles completely coated by carbon resisted both postdeposition treatments. However, further graphitization of the carbon coating by either of the two treatments was observed. Particles only partially coated by carbon were not protected, but sintered by annealing or dissolved in the acid. The magnetic properties of the as-made particles were measured by a vibrating sample magnetometer. The values of the saturation magnetic moment per gram of each type of metal particle are 56.21, 114.13, and 34.9 emu/g representing 26%, 71%, and 64% of the saturation moments of the bulk ferromagnetic elements iron, cobalt, and nickel, respectively. All the metal particles were shown to be ferromagnetic with a ratio of remnant to saturation magnetization MR/MS∼0.3 at room temperature (25 °C). In this article the detailed preparation and the properties of these carbon-coated metal particles will be discussed. © 1996 American Institute of Physics.

Notes: The plasma induced charging of surfaces in a plasma during semiconductor processing has been measured noninvasively using microelectromechanical devices. We have designed, modeled, and fabricated microcantilevers to act as charge sensing probes. The devices exhibit a mechanical deformation when charged, which is probed in situ by optical techniques, or measured by optical inspection after removal from plasma. Charging voltage measurements in a parallel-plate reactive-ion-etching reactor show that more charging is evident at the electrode edge, and that the charging is a strong function of input rf power, chamber pressure, and flow rate of gases. © 1996 American Institute of Physics.

Notes: Coherent structures and the dynamics of a neutrally stratified planetary boundary layer flow are studied through a large eddy simulation, which includes surface roughness, Coriolis force, and a capping inversion. Quadrant analysis and flow visualization show that low-speed negative momentum flux (ejection) is the dominant feature throughout most of the boundary layer. The initiation of vortical structures is observed to be associated with vorticity sheets and pressure maxima, which are formed dynamically when low-speed negative momentum flux collides with either high-speed negative momentum flux (sweep) or the mean flow. Four dimensional conditional averages are used to study the statistical behavior of ejections and sweeps. The shape, strength, lifetime, and origin of the conditionally sampled structures at three different heights are discussed. Near the surface, sweeps are observed to induce ejections when colliding with the surface. The evolution of sweep-induced ejections near the wall is discussed. © 1996 American Institute of Physics.

Notes: The techniques of resonant two-photon ionization (R2PI) and pulsed field ionization (PFI) were used to measure absorption spectra of ortho-chlorotoluene (S1, A˜ 1A1) and of ortho-chlorotoluene+ (D0, X˜ 2A1; the cation ground state) for internally cold molecules in a pulsed nozzle expansion. The adiabatic ionization potential is 71 318±5 cm−1=8.8423±0.0006 eV. Most of the observed low lying torsion–vibrational structure in both S1 and D0 can be assigned using a one-dimensional torsional model plus low frequency vibrational modes whose identity is corroborated by the ab initio normal modes of D0. The intensities of certain weak, forbidden torsion–vibration combination bands in the S1–S0 spectrum are well predicted by a nuclear coordinate dependence of the electric dipole transition moment. The threefold methyl torsional barrier is V3=144.2±2.0 cm−1 in S1 and V3=456.5±2.0 cm−1 in D0. Ab initio calculations at the HF/6-31G* level find V3=481 cm−1 in S0 with the minimum energy conformation pseudo-trans, i.e., with one CH bond lying in the plane of the ring on the opposite side of the chlorine substituent. Spectral band intensities show that the minimum is pseudo-trans in S1 and D0 as well.In both S1 and D0, excitation of either of the two lowest frequency out-of-plane bending modes, ν38 or ν37, leaves the methyl torsional potential essentially unchanged. In S0, S1, and D0, the barrier is substantially larger for ortho-chlorotoluene than for ortho-fluorotoluene, consistent with greater steric repulsion between the 3p chlorine lone pair and the CH bond pairs. The effects of π excitation and π ionization on the barrier are similar in ortho-chlorotoluene and ortho-fluorotoluene. Apparently both chlorine and fluorine are weak π donors that have similar effects on the crucial ring CC bond orders closest to methyl. Both the S1 and D0 spectra reveal several examples of torsion–vibrational coupling which perturbs torsional state energies and produces extra bands. Simple zeroth-order models of energy levels and coupling strengths fit experimental frequencies and band intensities well. Deperturbation yields coupling matrix elements between torsion and out-of-plane bending vibrations that fall in the narrow range 6–15 cm−1 in all cases. For three different molecules with widely varying methyl rotor barriers from 10 to 450 cm−1, the magnitude of such coupling matrix elements is similar, always in the range 3–15 cm−1. This provides guidance for theoretical models of intramolecular vibrational energy redistribution. © 1996 American Institute of Physics.