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  • 2000-2004  (12)
  • 1995-1999  (36)
  • 1965-1969  (20)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 1057-1065 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Quasielastic light scattering (QLS) in the frequency interval 100–1000 GHz is measured in some polymers: polycarbonate, polybutadiene, polystyrene, and poly(methyl methacrylate). To describe the spectra, a model of the fast picosecond relaxation processes responsible for the QLS, which is based on the damping of the boson peak vibrations by the dynamic hole volume fluctuations, is used. Within the frame of the model, the intensity of the fast relaxation process is proportional to the fractional dynamic hole volume (which above the glass transition temperature Tg is known as the fractional free volume). The hole volumes can be measured using the positron annihilation lifetime spectroscopy (PALS). The comparison of the literature PALS data in the four polymers with the QLS shows an apparent correlation between the relaxation strength and the fractional dynamic hole volume in good agreement with the predictions of the model. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 7053-7057 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Inelastic neutron scattering spectra of DNA-fibers are analyzed using ideas formulated recently in the field of the glass transition. The analysis reveals two temperatures, namely, T∼180–200 K and T∼230 K, at which the dynamics of DNA exhibits qualitative changes. The former is similar to the glass transition temperature, whereas the latter is similar to the crossover temperature recognized now as an important point for the dynamics of the glass transition. Exactly in this temperature range many other hydrated biopolymers show some dynamic transition and strong slowing down of their functions. The crossover temperature appears to be close to the crossover temperature of bulk water. A possible relation of the dynamic transition to functions of biomolecules and also to the dynamic transition in the hydration shell is discussed. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 10189-10195 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Relaxation processes in polymethylmethacrylate were investigated using light scattering and mechanical relaxation techniques. The acoustic attenuation data cover the frequency range from 1 Hz to 17 GHz and the light scattering from 0.5 to 10 000 GHz. Analysis of the data in a broad temperature range (80–350 K) shows that the model of the asymmetric double-well potentials, traditionally used for description of the acoustic attenuation in glasses, cannot describe all the data consistently. It is shown that assuming an additional relaxation in GHz region with a constant loss spectrum provides a good agreement of the model with experimental data. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 3122-3124 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Using photoemission and inverse photoemission, we have been able to characterize the Cr2O3 oxide surface of CrO2 thin films. The Cr2O3 surface oxide exhibits a band gap of about 3 eV, although the bulk CrO2 is conducting. The thickness of this insulating Cr2O3 layer is twice the photoelectron escape depth which is about 2 nm thick. The effective Cr2O3 surface layer Debye temperature, describing motion normal to the surface, is about 370 K. From a comparison of CrO2 films grown by different techniques, with different Cr2O3 content, evidence is provided that the CrO2 may polarize the Cr2O3. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 4691-4698 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A model of the low-frequency Raman scattering intensity in glasses is proposed, which describes the spectrum in the region of the boson peak, typical of glasses. The model considers the boson peak as a result of first-order light scattering by harmonic quasilocalized vibrations. The amplitude, frequency, and polarization dependence of the light on the vibrational coupling coefficient C(ω) are estimated. The model predicts a linear frequency dependence of C(ω) in the region of the boson peak and the depolarization ratio as a function of the relative contribution of the longitudinal and transverse-type motions which comprise these quasilocal vibrational modes. Low-frequency Raman and Brillouin measurements have been made on SiO2 glass in order to check the predictions of the model regarding the amplitude and integrated intensity of the boson peak. The estimated ratio of these values to those of the Brillouin lines are in good agreement with experiment. Comparison of the theoretical and experimental values of the depolarization ratio for the boson peak shows a predominance of the transverse-type atomic motions in the low-frequency quasilocalized vibrational modes in glasses. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 401 (1999), S. 549-555 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Kyoto Protocol allows reductions in emissions of several ‘greenhouse’ gases to be credited against a CO2-equivalent emissions limit, calculated using ‘global warming potential’ indices for each gas. Using an integrated global-systems model, it is shown that a ...
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 431 (2004), S. 961-963 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The nature of the transformation by which a supercooled liquid ‘freezes’ to a glass—the glass transition—is a central issue in condensed matter physics but also affects many other fields, including biology. Substantial progress has been made in understanding this ...
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1090-6487
    Keywords: 75.10.−b ; 64.60.Ak ; 64.60.Cn ; 05.10.Ln
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We study the critical behavior of frustrated systems by means of the Padé-Borel resummed three-loop renormalization group expansions and numerical Monte Carlo simulations. Amazingly, for six-component spins, where the transition is second-order, both approaches disagree. This unusual situation is analyzed both from the point of view of the convergence of the resummed series and from the possible relevance of nonperturbative effects.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1090-6509
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The real part R s and the imaginary part X s of the surface impedance Z s=R s+ iX s of Tl2Ba2CaCu2O8−δ and YBa2Cu3O6.95 single crystals have been measured with high precision at frequency ω/2π=9.4 GHz in the temperature range 0〈T〈140 K. In the Tl2Ba2CaCu2O8−δ crystal a linear temperature dependence R s(T) has been found for T⩽50 K, and the magnetic field penetration depth λ(4.2 K)=X s(4.2 K)/ω μ 0≈3760 Å has been measured. Along with well known features of the function Z s(T) in high-quality YBa2Cu3O6.95 single crystals, such as the linearity of λ(T) and R s(T) for T〈T c/3 and a maximum of R s(T) at T∼T c/2, the linearity range of λ(T) extends to T≃50 K, and this curve has a plateau in the range 60〈T〈85 K. The curve of R s(T) in both the superconducting and normal states of YBa2Cu3O6.95 is well described by a two-fluid model with the electron-phonon mechanism of quasiparticle relaxation. A formula describing the curve of λ 2(0)/λ 2(T) throughout the studied temperature range is also given.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1432-0630
    Keywords: PACS: 61.72.Cc; 61.72.Ji; 73.61.Cw
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract.  Vacancy-related defects introduced into n-Si during annealing or aluminium diffusion at high temperatures (1000–1250 °C) have been studied. Different ambients (argon, nitrogen, vacuum and chlorine-containing atmosphere) were used to create a vacancy supersaturation during heat treatments. Three deep-level centers whose formation is governed by the presence of vacancies have been identified. They were characterized by the following temperature dependences of the thermal emission rate: e 3=7.92×107 T 2×exp(−0.455/kT), e 5= 2.64×106 T 2×exp(−0.266/kT), e 7=7.26×106 T 2×exp (−0.192/kT). The influence of different factors, such as heat-treatment conditions, concentration of oxygen and doping level in initial crystals, on center formation was studied. An asymmetric diffuse γ-ray scattering was observed near the surface of a crystal irradiated by thermal neutrons and annealed in a chlorine-containing atmosphere. This scattering is related to the formation of structural defects of the vacancy type. In the same region of the crystal, the concentration of the E7 center was one order of magnitude higher than that of other deep-level centers. Comparison of the γ-ray diffraction and deep-level transient spectroscopy (DLTS) data suggests that the formation of the center occurs under the conditions of Si supersaturation with vacancies.
    Type of Medium: Electronic Resource
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