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  • 1
    Electronic Resource
    Electronic Resource
    Novel Nitrido- and Oxo(phthalocyaninato) Complexes of Molybdenum, Tungsten and Rhenium (2000)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 1025-1030 
    Details
    ISSN: 1434-1948
    Keywords: Phthalocyanines ; Nitrides ; Oxo complexes ; Rhenium ; Molybdenum ; Tungsten ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl3 (M = Mo, W) is reported. In addition, the reaction of (tBu4Pc)WN (6) with PPh3 leading, after several steps, to the diamagnetic compound (tBu4Pc)WO (7) is described. The reaction of (tBu4Pc)ReN (9) with PPh3 leads to [(tBu4Pc)ReO]2 (12), and of [(C5H11)8Pc]ReN (10) with PPh3 leads, under different conditions, to {[(C5H11)8Pc]ReO}2O (11).
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
  • 2
    Electronic Resource
    Electronic Resource
    Synthesis of Ladder-Type Oligomers Incorporating Phthalocyanine Units (2000)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 303-311 
    Details
    ISSN: 1434-193X
    Keywords: Phthalocyanines ; Cycloadditions ; Ladder Oligomers ; Macrocycles ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The condensation of substituted diiminoisoindolines with alkyl-substituted 1,3,3-trichloroisoindolines results in the formation of the highly soluble metal-free phthalocyanines 9, 15. By the same methodology, metal-containing phthalocyanines such as 16, 18 are accessible from suitable metal salts. The precursors 24 and26 were obtained from the phthalocyanine 9 and tetracyclone. The generation of the phthalocyanines 23 and 25 possessing isobenzofuran moieties as diene subunits was accomplished; in the presence of excess 28, the tetracyclone-bisadducts 22 and 24 were transformed into the model compounds 29 and 30, while an excess of 20 or 9 leads to the appropriate trimer-oligomers 31 and 32.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
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