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  • 2000-2004  (10)
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Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 6589-6594 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Aluminum-trimethylphosphine and trimethylarsine have been prepared by pulsed laser vaporization. Their electronic spectra have been obtained for the first time, using pulsed field ionization zero electron kinetic energy (ZEKE) photoelectron spectroscopy. The ZEKE spectra reveal the information about adiabatic ionization energies, intermolecular and ligand vibrations, and charge effects on molecular geometries. In coordination with the experimental measurements, density functional theory has been used to calculate equilibrium geometries, vibrational frequencies, and bond dissociation energies for the neutral and ionic complexes. The calculations predict that ionization causes the most significant geometry changes in the Al–P–C or Al–As–C angles, in agreement with the experimental observations. The aluminum ion and atom bind phosphorus more strongly than arsenic in these species. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 7968-7974 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The gallium complexes were produced in pulsed molecular beams and studied with zero electron kinetic energy (ZEKE) photoelectron spectroscopy. Intermolecular vibrational frequencies and adiabatic ionization potentials (IPs) were obtained from ZEKE spectra. Ground electronic states were identified by combining the ZEKE spectra with quantum chemical and Franck–Condon calculations. Ga–NH3 has an IP of 40 135 cm−1 and metal-ligand stretching frequencies of 270 cm−1 (ωs+) in the ion and 161 cm−1 (νs) in the neutral. The IP of Ga–NH2CH3 is 39 330 cm−1, and the vibrational frequencies are 93 cm−1 (νb) for the Ga–N–C bending, 124 cm−1 (ωb+) for the Ga+–N–C bending, and 299 cm−1 (ωs+) for the Ga+–N stretching. The strength of the gallium–methylamine binding is stronger than that of the gallium–ammonia. The ground state of Ga–NH3 is 2A′(Cs) and that of Ga+–NH3 is 1A1(C3v). In contrast, Ga–NH2CH3 has two doublets, 2A′ and 2A″(Cs), with virtually the same energies, whereas Ga+–NH2CH3 has a 1A′(Cs) ground state. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 4565-4572 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Single-photon pulsed field ionization-zero electron kinetic energy photoelectron spectroscopy has been used to study the indium–methylamine complexes. The photoelectron spectra have been assigned using density functional theory and Franck–Condon calculations. The spectral assignments identify the symmetric In+–N stretch mode for In+–NH2CH3 (259 cm−1), In+–NH(CH3)2 (200 cm−1), and In+–N(CH3)3 (158 cm−1); In–N stretch for In–N(CH3)3 (110 cm−1); In+–N–C bend for In+–NH2CH3 (110 cm−1) and In+–NH(CH3)2 (120 cm−1); In–N–C bend for In–NH2CH3 (91 cm−1) and In–NH(CH3)2 (106 cm−1); and In+–N–H bend for In+–NH(CH3)2 (324 cm−1). Methyl substitutions for hydrogen atoms greatly influence the indium–nitrogen stretch forces and ionization potentials of the complexes. The indium–amine binding in these complexes includes orbital interaction and electrostatic forces. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 76 (2000), S. 1170-1172 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: TbFe12−xTix single crystals have been investigated by means of magnetic measurements. With decreasing temperature, a spin-reorientation transition from easy axis to easy plane occurs. The rate of decrease of spin-reorientation temperature with x is about −380 K/Ti. There exists a strong magnetocrystalline anisotropy in the basal plane. The anisotropy field Ba between [100] and [110] for the compound TbFe11.15Ti0.85 is as high as 35 T which is about three times Ba in the axial direction. With increasing x, the easy magnetization direction at low temperatures in the basal plane changes from [110] for x=0.85 to [100] for x=1.0. The composition dependence of anisotropy can be understood in terms of a change of the crystal field parameters Anm due to substitution of Ti for Fe. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chester : International Union of Crystallography (IUCr)
    Journal of synchrotron radiation 8 (2001), S. 229-231 
    ISSN: 1600-5775
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: The fluorescence EXAFS spectra for a copper thin film with a thickness of 3000Å measured at 300K, 350K and 400K were analyzed by the regularization method to directly obtain the radial distribution. The pair distribution was almost symmetric for 300K but asymmetric for 350K and 400K. This indicates that the atoms in copper vibrate anharmonically near room temperatures. The anharmonicity and the skewness of the asymmetric distribu-tion increases as temperature increases.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 274-276 (Oct. 2004), p. 463-468 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 261-263 (Apr. 2004), p. 1683-1688 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Tires are the only means for connecting a vehicle to the ground. The forces such as driving force, braking force, rotation force and the like occur on the contact surface between the tire and the ground and thus determine the motion of the vehicle. A general tire generates separation that continues to repeat tension and compression by the load of the vehicle. The separation raises the temperature of the tire, resulting in loosening between tire members and in the end damages the tire. Since a tire has a composite structure, which consists of rubber and reinforcements, many problems arise in the analysis of the tire. In this study, a tire of a composite structure was analyzed for heat transfer under the same condition as in the running state, so as to examine temperature distribution at tread. Theoretical results were verified using a thermal vision camera a non-contact non-destructive temperature measurement instrument
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 224-226 (June 2002), p. 535-538 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 261-263 (Apr. 2004), p. 1385-1390 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The purpose of this research is stability estimation of plant structure through classification andrecognition about welding flaw in SWP(Spiral Welding Pipe). And, In this research, we usednondestructive test based on ultrasonic test as inspection method, and made up inspection robot inorder to control of ultrasonic probe on the SWP surface, and programmed to signal processing codeand pattern classifying code by user made programming code. Inspection robot is simplyconstructed as 2-axes because of welding bead with fixed pitch. So, inspection of welding part canbe possible as composition of inspection part for tracking on welding line. For evaluation of flawsignal is reflected on welding flaw, user-made program codes are composed of signal processingand Bayesian classifier and perceptron neural network and back-propagation neural network. Andthen, we confirmed to superiority of neural network method compared with Bayesian classifier forclassification and recognition rate. According to this result, we selected back-propagation neuralnetwork as classification and recognition method about the system of SWP stability Estimation[2].Through this process, we proved efficiency on the system of SWP stability Estimation, andconstructed on the base of the system of SWP stability Estimation for the application in industrialfields
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-6865
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract The development of rat fundic gland was studied by immunohistochemistry using a recently developed monoclonal antibody, HIK 1083, at both light and electron microscope levels. Antibody HIK 1083 recognized oligosaccharides with a non-reducing terminal α-linked N-acetylglucosamine (GlcNAc) residue. In the developing rat fundic gland, cells expressing α-GlcNAc residues were discernible from day 19.5 of gestation and continued to exist till adult. The distribution of the α-GlcNAc expressing cells was consistent with that described previously for cells reacting to Griffonia simplicifolia lectin (GSA-II) in all developmental stages. These cells were located at the bottom of the fundic gland when they first appeared. With the elongation and maturation of the gland, these cells moved upwards and were finally restricted in the neck region of the gland. Combining previous reports and the present electron microscopical observations, HIK 1083-positive cells in the adult rat fundic gland are mucous neck cells. The interaction between antibody HIK 1083 and GSA-II lectin was investigated. GSA-II prevented the subsequent binding of HIK 1083, while HIK 1083 did not prevent GSA-II binding to mucous neck cells. Our results suggested that α-GlcNAc residues exist in rat fundic gland from day 19.5 of gestation and continue to exist till adult. Cells expressing α-GlcNAc residues appeared as typical mucous neck cells from postnatal four weeks.
    Type of Medium: Electronic Resource
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