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  • 1995-1999  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 84 (1998), S. 648-650 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of deposition temperature and growth rate on the bond structure of hydrogen free carbon films has been investigated. A sharp transition temperature of the sp3 content of the carbon films as a function of deposition temperature has been reported several times. The value of this transition temperature has varied from 150 to about 300 °C depending on the growth mechanism. In this article, high values varying from 300 to 400 °C for the transition temperature are reported. High momentary growth rates of up to 2000 nm/s have been obtained by using pulsed vacuum arc deposition. The transition temperature has been observed to depend on the momentary growth rate of the carbon film. The transition has been explained to be a relaxation process which includes diffusion of carbon atoms at the near surface. The results have been analyzed by using a model which was originally developed for radiation enhanced diffusion. An activation energy of 0.65 eV was obtained. The model also predicts qualitatively the transition temperatures in the case of the lower deposition rates reported in literature. For the frequency factor of the diffusion coefficient a value of the order of 10−8 cm2/s was obtained. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 7248-7254 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of enhanced atomic mobility on the growth of hard carbon films was examined. Tetrahedrally bonded amorphous carbon films were deposited by condensing energetic carbon ions using an arc-discharge deposition method. The deposition temperature varied between 50 and 400 °C. The dependence of elastic properties on deposition temperature was examined by determining the frequency-dependent propagation velocity of ultrasonic surface acoustic waves induced by a laser. A remarkable decrease in elastic coefficient was revealed above the deposition temperature of 300 °C and complete relaxation was obtained at 400 °C. This observation was analyzed by using a simple model which was in turn supported by molecular dynamics simulations. The relaxation turns out to be a thermally activated, dynamic process with an activation energy of 0.57 eV. Possible relaxation mechanisms associated with the migration of atoms or defects on a growing surface are discussed. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 3167-3169 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-2711
    Keywords: diamond-like carbon ; ta-C ; a-C:H ; load-carrying capacity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Diamond-like carbon (DLC) coatings have shown excellent tribological properties in laboratory tests. The coatings have also been introduced to several practical applications. However, the functional reliability of the coatings is often weakened by adhesion and load-carrying capacity related problems. In this study the load-carrying capacity of the coating/substrate system has been evaluated. The DLC coatings were deposited on stainless steel, alumina and cemented carbide with two different deposition techniques: the tetrahedral amorphous carbon (ta-C) coatings were deposited by a pulsed vacuum arc discharge deposition method and the hydrogenated carbon (a-C:H) films by radio frequency (r.f.) plasma deposition method. The load-carrying capacity of the coated systems was evaluated using a scratch test, Rockwell C-indentation test and ball-on-disc test. The effect of substrate material, substrate hardness, coating type and coating thickness was studied. An increase in substrate hardness increased the load-carrying capacity for the coated systems, as expected. The two coating types exhibited different performance under load due to their different physical and mechanical properties. For the load-carrying capacity evaluations the ball-on-disc configuration was found to be most suitable.
    Type of Medium: Electronic Resource
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