ISSN:
1573-9171
Keywords:
electroreduction
;
alkynyl halides
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Reduction of phenylethynyl halides PhC≡CHal (Hal = I (1), Br (2), Cl (3)), diiodoacetylene (4), (phenylethynyl)triphenylphosphonium bromide (5), and related compounds in THF was studied by means of cyclic voltammetry using a glassy-carbon electrode. Compounds1–5 are reduced with cleavage of the C-Hal bond, and the reduction potentials increase in the order3 〈2 〈1 〈4 〈5.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00707244
Permalink