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  • 1
    ISSN: 1432-0819
    Keywords: Key words Fumaroles ; Fluid chemistry ; δD value ; δ18O value ; Volcanic surveillance ; Vulcano Island
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Variations in δD and δ18O values with H2O contents and outlet temperatures indicate that the fumaroles of La Fossa crater have discharged mixtures of magmatic water and marine hydrothermal water, since 1979. The contribution of meteoric water was low in the period 1979–1982 and very low afterwards. The δ18O values of the marine-hydrothermal component of +5 to +7.2ö are due to isotopic exchange with the 18O-rich silicates of the rocks under high-temperature and low-permeability conditions. The δ18O value of the magmatic end-member is generally +3.5 to +4.3ö, although values as high as +5.5 to +6.5ö were reached in the summer of 1988, when magma degassing appears to have extended into the core of the magma body. The δD values of the end-member were close to –20ö, typical of andesitic waters. Both the isotopic values and chemical data strongly support a 'dry' model, consisting of a central magmatic gas column and a surrounding hydrothermal envelope, in which marine hydrothermal brines move along limited fracture zones to undergo total evaporation on approaching the conduits of magmatic fluids.The vents at the eastern and western boundaries of the fumarolic field are fed by fluids whose pressure is governed by the coexistence of vapor, liquid and halite, giving rise to a high risk of phreato magmatic explosions, should magma penetrate into these wet environments. Most La Fossa eruptions were triggered by an initial hydrothermal blast and continued with a series of phreatomagmatic explosions.The fluids discharged by the Forgia Vecchia fumaroles are mixed with meteoric water, which is largely evaporated, although subordinate loss of condensed steam may be responsible for scrubbing most of the acidic gas species. The temperatures and pressures, and the risk of a sudden pressure increase, are low.A boiling hydrothermal aquifer at 230°  C is present underneath the Baia di Levante beach. This area has a minor risk of hydrothermal explosions.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0819
    Keywords: Key words Sulfur isotopes ; Magma degassing ; Somma-Vesuvius volcanic complex
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Sulfur contents and δ34S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key parameter controlling the 34S/32S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ34S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions.
    Type of Medium: Electronic Resource
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