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  • 1
    Electronic Resource
    Electronic Resource
    The kinetics of diastereomeric amino acids with o-phthaldialdehyde (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Chirality 3 (1991), S. 471-475 
    Details
    ISSN: 0899-0042
    Keywords: amino acids ; kinetics ; epimers ; OPA ; postcolumn reaction detection ; fluorescence detection ; amino acid racemization ; dating methods ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the reaction of the amino acid epimers L-isoleucine, D-alloisoleucine, L-threonine, and D-allo-threonine with o-phthaldialdehyde and mercaptoethanol were determined at 25°C. L-Isoleucine reacts faster than its D-epimer whereas L-threonine reacts slightly slower than its D-epimer. In the case of isoleucine, the consequence can be an allo/iso ratio which in the worst case is 25% too low if these amino acids are quantified by liquid chromatography and o-phthaldialdehyde fluorescence detection. The effect on dating of fossils by amino acid racemization is discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/chir.530030611
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  • 2
    Electronic Resource
    Electronic Resource
    Über ein Oxidchlorid des Calciums: Ca4OCl6 (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 596 (1991), S. 89-92 
    Details
    ISSN: 0044-2313
    Keywords: Calcium oxychloride ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: An Oxychloride of Calcium: Ca4OCl6Ca4OCl6 (hexagonal, P63mc, Z = 2), a = 905.8(3), c = 686.3(4) pm, (R = 0.031) crystallizes as colourless needles from reducing melts (CaCl2, Ca) that contain small amounts of „oxygen“. It contains „isolated“ tetrahedral units [Ca4O] and is isotypic with e.g., Ba4OCl6, Yb4OCl6 and K6HgS4. Ca4OCl6 does not form in the dehydration process of, for example, CaCl2 · 6 H2O.
    Notes: Ca4OCl6 (hexagonal, P63mc, Z = 2, a = 905.8(3)); c = 686.3(4) pm, (R = 0,031) kristallisiert in Form farbloser Nadeln aus „reduzierenden Schmelzen“ (CaCl2, Ca), die wenig „Sauerstoff“ enthalten. Es enthält „isolierte“ tetraedrische [Ca4O]-Einheiten und ist isotyp mit z. B. Ba4OCl6, Yb4OCl6 oder K6HgS4. Ca4OCl6 entsteht nicht beim Entwässern von z. B. CaCl2 · 6 H2O.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19915960112
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  • 3
    Electronic Resource
    Electronic Resource
    Polyelectrolyte glasses with linear and nonlinear optical properties (1991)
    Weinheim : Wiley-Blackwell
    Advanced Materials 3 (1991), S. 153-156 
    Details
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/adma.19910030308
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  • 4
    Electronic Resource
    Electronic Resource
    The function of polymers in the tape casting of aluminaThe work was supported by the Bundcsministcrium fur Forschung and Technologie, FRG (No. 03M2704). [AMR88] (1992)
    Weinheim : Wiley-Blackwell
    Advanced Materials 4 (1992), S. 73-81 
    Details
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/adma.19920040203
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  • 5
    Electronic Resource
    Electronic Resource
    Tetraphenylporphyrins as coupling reagents and corrosion inhibitorsDedicated to Professor Dr. H.-F. Grützmacher on the occasion of his 60th birthday (1992)
    Weinheim : Wiley-Blackwell
    Advanced Materials 4 (1992), S. 496-498 
    Details
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/adma.19920040709
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  • 6
    Electronic Resource
    Electronic Resource
    Electroluminescent devices based on poly(methylphenylsilane)This work was supported by the Deutsche Forschungsgemeinschaft (Sonderforschungsbereich No. SFB-213) and the Fonds der Chemischen Industrie. We also thank P. Strohriegl and W Joy for synthesizing PMPS, H. Kaul for providing the TOF data of PMPS, and K. Bauer for supplying solvents. H. S. is on leave from NTT Opto-Electronics Laboratories, Japan. (1993)
    Weinheim : Wiley-Blackwell
    Advanced Materials 5 (1993), S. 743-746 
    Details
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/adma.19930051013
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  • 7
    Electronic Resource
    Electronic Resource
    Schwermetall- und chloridhaltige Filterstäube. I. Phasenanalysen und Modellversuche zum Recycling (1993)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 335 (1993), S. 255-261 
    Details
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Flue Dusts Containing Heavy Metal Ions and Chloride.I. Phase Analysis, Model Experiments for RecyclingFour flue dusts from a cement factory, an electric-furnace steelmaking plant and a municipal waste plant were analyzed by powder diffraction methods. Chloride combines above all with alkali ions or heavy metal ions, especially yielding PbCl2 and KPb2Cl5. The controlled sublimation of these chloride compounds in open crucibles was developed and optimized in our laboratory. Between 850°C and 1150°C and at reaction times from 30 min up to 12 h, the chloride content decreases to below 0.1 wt-%. The sublimed phase mainly consists of alkali and lead chloride. Zinc is found in the flue dust as oxide and is enriched during this process. Recent investigations with a small waelz kiln give analogous results. With our procedure, the manufacturer by himself is able to exploit flue dusts containing a large amount of heavy metal elements and chloride which cannot be deposited. The remaining product contains mainly zinc oxide which can be recycled in the zinc industry or returned to the production process. The sublimed chloride compounds may be recycled in the potash industry.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19933350307
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  • 8
    Electronic Resource
    Electronic Resource
    Modelling of coadsorption of different-sized molecules by using methods of statistical thermodynamicsDedicated to Professor Dr. Dr. h.c. Hanns Hofmann on the occasion of his 70th Birthday (1994)
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 17 (1994), S. 119-126 
    Details
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Using methods of statistical thermodynamics, adsorption isotherms for the description of multicomponent chemisorption of different-sized molecular species are derived by assuming the adsorbing surface to be energetically homogeneous and by neglecting lateral interactions between the adsorbed particles. In the first part of this contribution, the adsorption equilibria for a mixture of different-sized chain molecules adsorbed on a lattice of coordination number z are discussed supposing each unit of a given chain to bind to one adsorption site only. In the second part, the coadsorption of molecular species consisting of a different number of segments on a continuous surface is treated. A comparison of the predicted to the measured isotherms for the coadsorption of two freon species on activated carbon shows that the proposed equations describe the results of the coadsorption measurements sufficiently well, provided the adsorption data for the pure components have been determined experimentally.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ceat.270170209
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  • 9
    Electronic Resource
    Electronic Resource
    Incapability of Gluconobacter oxydans to produce tartaric acid (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 40 (1992), S. 183-186 
    Details
    ISSN: 0006-3592
    Keywords: Gluconobacter oxydans ; 5-ketogluconic acid ; tartatic acid ; vanadate ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dependence of tartaric acid production by Gluconobacter oxydans ssp. oxydans ATCC 19357 and G. oxydans ssp. suboxydans ATCC 621 on vanadate was investigated. It was found with both organisms that trataric acid could only be produced in a medium containing vanadate (NH4VO3). A proposed intermediate of the tartaric acid metabolism in G. oxydans, 5-ketogluconic acid, was tested on its reactivity in the presence of the oxidizing catalyst vanadate. It could be shown that 5-ketogluconic acid and the catalyst vanadate, but not the activity of G. oxydans, were responsible for the formation of tartaric acid. G. oxydans was not able to produce tartaric acid by itself. The stereochemical identity of the formed tartaric acid could be identified as the L-(+)-type. Oxalic acid was formed from 5-ketogluconic acid with vanadate in the absence and in the presence of G. oxydans. The ratio of oxalic acid to tartaric acid was 1:1.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260400126
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  • 10
    Electronic Resource
    Electronic Resource
    Chemostat cultivation of Candida blankii on sugar cane bagasse hemicellulose hydrolysate (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 40 (1992), S. 353-358 
    Details
    ISSN: 0006-3592
    Keywords: Bagasse hemicellulose hydrolysate ; chemostat ; Candida blankii ; D-xylose ; single cell protein ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A Candida blankii yeast isolate was grown in sugar cane bagasse hemicellulose hydrolysate at 38°C in carbon-limited chemostat culture. The pretreatment of the acid hydrolysate prior to microbial cultivation consisted of partial neutralization with ammonia and sodium hydroxide, plus the addition of phosphorus, which was the only other growth-limiting nutrient apart from nitrogen. The cell yield coefficient on nitrogen was 16.78. The critical dilution rate was higher (0.35 h-1) in diluted hydrolysate than in undiluted hydrolysate (0.21 h-1). In undiluted hydrolysate at a dilution rate of 0.1 h-1 and pH 4, where aseptic procedures proved unnecessary, the cell and protein yield coefficients were 0.53 and 0.26, respectively, and no residual carbon substrates (D-xylose, L-arabinose, D-glucose, and acetic acid) were detected. The cell yield on oxygen increased linearly as a function of dilution rate. The cellular content of protein, carbohydrate, and RNA also increased with an increase in dilution rate, whereas the DNA content decreased slightly. C. blankii has considerable potential for the production of single cell protein from hemicellulose hydrolysate, because of its ability to utilize all of the major carbon substrates in the hydrolysate at a low pH and at a relatively high temperature with a high protein yield. © 1992 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260400304
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