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  • 1990-1994  (5)
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  • 1
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: 294 transitions were measured by velocity modulation spectroscopy using a difference frequency laser system with a D2/O2 discharge and assigned to the ν3 (antisymmetric stretch) band of D3O+. A simultaneous analysis of this data with the ν2 band spectra reported by Sears, et al. [J. Chem. Phys. 83, 2676 (1985)] yielded a refined set of parameters for both the ground and the excited states of both bands. The ν3 bandcenters are 2629.6512(39) and 2624.2376(47) cm−1 for the s–s and a–a inversion components, respectively.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 6935-6946 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The absolute quantum yields (Φ) for OH production from 193 and 248 nm photolysis of HNO3 and H2O2 are measured at room temperature using flash kinetic spectroscopy in a flow tube. The OH radicals are produced by excimer laser photolysis and probed via direct absorption of high resolution, tunable IR laser light. The resulting quantum yields are found to be ΦHNO3193=0.47±0.06, ΦH2O2193=1.22±0.13, ΦHNO3248=0.75 ±0.10, and ΦH2O2248= 1.58±0.23. These results indicate quantum yields for both precursors at both wavelengths which are less than the maximum possible values of 1 for HNO3 and 2 for H2O2. The present measurements are discussed in light of contrasting results suggested from other work.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 8009-8018 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The perturbed (v,b,K,n)=(1210),(1113)←(0000) band of ArHF is observed in a tunable laser/slit supersonic expansion spectrometer. The (1210) level correlates with j=2 rotation of the HF within the complex and therefore provides a test of high-order terms in a Legendre expansion of the intermolecular potential. Transitions to (1113) are observed due to intensity sharing with (1210), induced by a strong homogeneous (J-independent) perturbation that is analyzed quantitatively. The (1113) level has three quanta of Van der Waals stretch and thus probes the radial dependence of the potential close to the dissociation limit. The vibrational and rotational assignment is made possible by predictions based on the new H6(4,3,2) intermolecular potential of Hutson [J. Chem. Phys. 96, 6752 (1992)], which agree nearly quantitatively with experiment.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 42-48 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A novel, simple, and inexpensive calibration scheme for a continuous-wave difference frequency spectrometer is presented, based on the stabilization of an open transfer cavity by locking onto the output of a polarization stabilized HeNe laser. High frequency, acoustic fluctuations of the transfer cavity length are compensated with a piezoelectric transducer mounted mirror, while long term drift in cavity length is controlled by thermal feedback. A single mode Ar+ laser, used with a single mode ring dye laser in the difference frequency generation of 2–4 μm light, is then locked onto a suitable fringe of this stable cavity, achieving a very small long term drift and furthermore reducing the free running Ar+ linewidth to about 1 MHz. The dye laser scan provides tunability in the difference frequency mixing process, and is calibrated by marker fringes with the same stable cavity. Due to the absolute stability of the marker cavity, precise frequency determination of near infrared molecular transitions is achieved via interpolation between these marker fringes. It is shown theoretically that the residual error of this scheme due to the dispersion of air in the transfer cavity is quite small, and experimentally that a frequency precision on the order of 1 MHz per hour is routinely obtained with respect to molecular transitions.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Physical Chemistry 45 (1994), S. 367-399 
    ISSN: 0066-426X
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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