Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • 1985-1989  (6)
  • Chemistry  (6)
  • Analytical Chemistry and Spectroscopy  (1)
  • Patch clamp
  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 3029-3056 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: This study was undertaken to determine how milled glass fibers affect the fatigue resistance of reaction injection molded (RIM) nylon 6. Specifically the effects of glass content, fiber length, orientation, and surface treatment were investigated. The fatigue crack growth rates for unfilled and glass-filled samples were observed to follow the well-known Paris equation in terms of dependence on cyclic stress intensity factor. For the unfilled nylon a line shaped zone was observed in advance of the crack tip. Fractography results suggest that the zone was the projection of the actual crack tip profile through the thickness of the sample rather than a distinct plastic or deformation zone. The fatigue fracture surface exhibited a patchy type structure with features 50-150 μm in size, suggesting a void coalescence type of mechanism as has been reported for injection molded nylons. A diffuse damage zone, several millimeters in size, was observed at the crack tip for the glass-filled RIM nylon 6. The zone was observed to pulsate with the applied oscillating load. The growth of the damage zone volume with increasing crack length (and thus increasing stress intensity factor range) followed the Paris law, as did the crack growth rate data. The damage mechanism is attributed to void formation and microcracking at the fiber-matrix interface. The results of this study show that, for milled glass-reinforced RIM nylon 6, the crack growth rates were much more rapid than observed for injection-molded nylon 6 containing chopped glass fibers. This difference is attributed to the greatly reduced glass fiber lengths for the milled glasses.
    Zusätzliches Material: 19 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 328 (1986), S. 199-204 
    ISSN: 0021-8383
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Structure of New Systems of ThiatriazinesDepending on the nucleophilicity of exocyclic nitrogen in 2-guanidino-benzimidazole-1-carbimidic esters and 1-carbamides cyclization with N-sulfinyl amines leads to new 3-amino-1λ4, 2,4,6-thiatriazino[2,3-a]benzimidazole-1-oxide-5-carbimidic esters (3), 1-oxide-5-carbamides (5) and 3-(4-chlorphenylamino)-1-toluene-sulfonylimino-1λ4,2,4,6-thiatriazino[2,3-a]benzimidazole-5-carbimidic ester (7).
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 19 (1987), S. 503-512 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reaction IO + CH3SCH3 → products (3) was studied at room temperature and near 1 Torr pressure of He, using the discharge flow mass spectrometric technique. The rate constant was found to be k3 = (1.5 ± 0.5) × 10-11 cm3 molecule-1 s-1. CH3S(O)CH3 was detected as a product suggesting the following channel: IO + CH3SCH3 → CH3S(O)CH3 + I. The rate constant of the reaction IO + IO → products (1) was also measured: k1 = (3 ± 0.5) × 10-11 at 298 K and 1 Torr pressure. The atmospheric implication of reaction (3) is discussed. The results indicate that this reaction could be a potential important sink of CH3SCH3 in marine atmosphere.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 24 (1986), S. 21-30 
    ISSN: 0749-1581
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The 13C NMR chemical shifts of 74 N-acylated 2-aminobenzimidazoles were determined and assigned. The chemical shifts are discussed as a function of electronic and spatial substituent effects. Line broadening for certain C signals are traced to prototropy at N-1 and N-3, and N-3 and Nexo.
    Zusätzliches Material: 6 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1247-1261 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reactions of OH radicals with dimethylsulfide (DMS) diethylsulfide (DES), tetrahydrothiophene (THT), and thiophene have been studied at room temperature for DES and THT, at 273, 293, and 318 K for DMS, and at 293 and 318 K for thiophene by the discharge flow EPR technique in a halocarbon wax coated reactor. The following rate constants were obtained at room temperature. For the reaction OH + DMS (1), a very low temperature dependence was noticed.Some additional results concerning the mass spectrometric analysis of the products are also reported.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 20 (1988), S. 897-907 
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A kinetic study of the reactions of H atoms with CH3SH and C2H5SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 ± 0.20) × 10-12 for the reaction H + CH3SH (1) and k2 = (2.40 ± 0.16) × 10-12 for the reaction H + C2H5SH (2). Units are cm3 molecule-1 s-1. A mass spectrometric analysis of the reaction products and a computer simulation of the reacting systems have shown that reaction (1) proceeds through two mechanisms leading to the formation of CH3S + H2 (1a) and CH3 + H2S (1b).
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...