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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 26 (1987), S. 1072-1079 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 5944-5946 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The lattice Anderson model is considered with two nondegenerate orbitals per site (c and f ). The Hamiltonian matrix is constructed in a localized representation on a four site, tetrahedral cluster. All the eigenvalues are obtained for any occupancy by explicit diagonalization, using symmetry to reduce the problem to manageable size. Thermodynamic functions are calculated. Emphasis in this work is placed on the strong interaction–weak hybridization sector of the model. The behavior of the model is quite complex, with five different regions delineated.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 980-983 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The real and imaginary parts of ac susceptibility of a sintered Y1Ba2Cu3O7−δ superconductor were measured before and after powdering. The temperature-dependent susceptibility may be separated into two contributions, one sensitive and the other relatively insensitive to the magnitude of the measuring field. The former is partially suppressed by coarsely crushing the sample. It is completely suppressed after finely powdering, whereupon the susceptibility curves become insensitive to the magnitude of the measuring field. Several models apparently consistent with the results are discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 4344-4348 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the effects of sequential pressure cycling (0–2.8 GPa at room temperature) on the critical currents in a YBa2Cu3O7−δ superconductor. From both low- (0–100 Oe) and high- (up to 5.5 T) field dc magnetic data we identify the contributions to the total critical currents arising from inter- (transport) and intragranular aspects of the superconductor. In our studies, we find that above the pressure limit (≤1.0 GPa) of reversible changes the transport critical current is found to irreversibly decrease by as much as 40%–50% for cycling at 2.8 GPa. However, the intrinsic contribution to the critical current is unaffected. Concomitantly two lower critical fields H@B|c1 and Hc1 are found necessary to fully characterize the low-field hysteretic loops for these superconductors. One consequence of pressure cycling is that we find H*c1, which signifies the intergranular connectivity, is reduced to lower values. The effects of pressure cycling on the real and imaginary (lossy) components, χ'(T) and χ‘(T), of the low-field ac susceptibility are found to be consistent with the dc data.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 4215-4215 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new class of Fe-, Co-, Ni-, Cu-, and Ge-based ductile ribbons in which an amorphous matrix containing less than 12 vol. % of a fine dispersion of 0.1–3-μm size particles of immiscible elements M=Pb, Bi, Sn, or In have been produced by a modified melt-quenching technique. The Fe- and Co-based alloys containing Bi and Pb are found to be ferromagnetic above room temperature and also superconducting at temperatures in a range 7–9 K depending on the alloy. The saturation magnetization in these usual alloys range from 92 emu/gm for Co-Si-B-Pb-Bi to 15 emu/g for Fe-P-Pb-Bi at 77 K. At the superconducting transition the resistivity typically is found to drop by 2–3 orders of magnitude with a transition width ∼0.5 K before the "zero'' resistance value is reached. In all the alloys studied the T dependence of the resistivity shows a typical metallic behavior despite its high magnitude (a few thousand μΩ cm in some cases). Extremely high values are found for the upper critical fields (1.6–1.72 T at 4.2 K) with critical current densities typically around 1.3×107 A m−2 at 4.2 K. For Ge-Pb-Bi-Sn Hc2 values of 5 T are obtained at 3 K. Along with detailed studies of magnetic and superconducting properties, extensive TEM, and x-ray characterization data will also be presented. Attempts to explain the above described behavior in terms of proximity, percolation, and surface properties at the dispersed Pb, Bi particles are found to be unsatisfactory. As far as we know there exists no theory that can explain the co-existence of ferromagnetism and superconductivity of the type described above. Time permitting, we will also discuss our recent work on high Tc oxide materials produced by melt-quenching techniques. Thus amorphous composite materials exhibiting unique and useful characteristics which cannot be achieved for homogeneous amorphous alloys can be produced by melt quenching. These materials are of importance both for scientific and engineering points of view.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 3249-3249 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ion-beam mixing has become a new and powerful technique to amorphize alloys systems in an extended concentration range while at the same time providing much more homogeneous films. In this paper we will present magnetic, thermal, and glavanomagnetic property studies on binary Fe-Zr amorphized alloys produced by irradiating multilayers of evaporated Fe-Zr crystalline films with Kr, Xe, and/or Ar ions at 500 keV with doses of 2×1016 ions/cm2. The final compositions of the amorphized films, containing 10–27 at. % Zr, were determined from Rutherford backscattering measurements. Further characterization of these x-ray amorphous films have been carried out using TEM and Mössbauer techniques. Comparison with melt-spun amorphous alloys reveals that the frequently quoted model for amorphization in ion-irradiation experiments of fast quenching spikes is questionable. From low-field ac-susceptibility data we obtain the magnetic phase diagram which is then compared with that obtained for melt-spun alloys. All the ion-beam-mixed alloys are found to be "ferromagnetic'' below room temperature which is then followed by a "spin-glass-like'' behavior below TC. It thus appears that the line of "spin-glass transitions'' extends to a much wider concentration range than known before. Electrical and Hall resistivity data along with their temperature dependencies will also be discussed in relevance to the loss of long-range order in these systems at lower temperatures.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 1592-1600 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new model is proposed to interpret the breakdown phenomenon of dielectric thin films such as SiO2 films over the whole range of an applied field. It is suggested that two main mechanisms are responsible for the dielectric breakdown which is influenced by the geomorphic and physical parameters, and the examination conditions. One of the mechanisms is the avalanche breakdown, the so-called intrinsic type, which is caused by impact ionization. The other, the extrinsic type, is the filament-heating transport which induces a destructive breakdown. A simple mathematical model invoking the role of photon absorption is constructed to describe the effects of the band gap and the insulator thickness on the dielectric breakdown. It can be deduced from the model that (i) the mean distance of impact ionization is equivalent to the minimum thickness of the film generating the impact ionization and (ii) the probability of impact ionization is a function of the width of the band gap of the insulator under an applied field. Finally, effects of various processing conditions on the breakdown mechanisms and the dielectric strength are discussed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 2489-2500 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have calculated the initial magnetization curves and complete hysteresis loops for hard type-II superconductors. The critical-current density Jc is assumed to be a function of the internal magnetic field Hi according to Kim's model, Jc(Hi)=k/(H0+||Hi||), where k and H0 are constants. As is the case for other critical-state models, additional assumptions are that bulk supercurrent densities are equal to Jc, and that the lower critical field is zero. Our analytic solution is for an infinite orthorhombic specimen with finite rectangular cross section, 2a×2b (a≤b), in which a uniform field H is applied parallel to the infinite axis. Assuming equal flux penetration from the sides, we reduced the two-dimensional problem to a one-dimensional calculation. The calculated curves are functions of b/a, a dimensionless parameter p=(2ka)1/2/H0, and the maximum applied field Hm. The field for full penetration is Hp=H0[(1+p2)1/2−1]. A related parameter is H@B|m=H0[(1+2p2)1/2−1]. Hysteresis loops were calculated for the different ranges of Hm : Hm〈Hp, Hp〈Hm〈H*m, and H@B|m〈Hm. The equations for an infinite cylindrical specimen of radius a are the same as those for a specimen with square cross section, a=b. In the limit p(very-much-less-than)1 and a=b, our results reduce to those of the Bean model (Jc independent of Hi) for cylindrical geometry. Similarly, in the limit p(very-much-less-than)1 and b→∞, the results are the same as those for a slab in the Bean model. For H〉1.5 Hp, or H〉0 when p(very-much-less-than)1, the width of the hysteresis loop ΔM may be used to deduce Jc as a function of H: Jc(H)=ΔM(H)/[a(1−a/3b)].
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 2533-2536 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: ac and dc magnetic susceptibilities were studied for relatively dense single-phase YBa2Cu3O7−x samples. The data are discussed in terms of sample defects.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 2656-2663 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Three-dimensional computer simulation is carried out for the aggregation process of colloids using the sticky sphere model proposed in the previous paper. Time evolution of the structure of aggregates and macroscopic viscosity is studied when a shear flow is started in a suspension of the sticky spheres. In the transient state, the viscosity is found to increase in sigmoidal manner in agreement with real experiments. This phenomena is shown to be caused by the cooperative aggregation. In the steady state, it is found that (i) as the volume fraction increases, the structure transforms from compact cluster to loose network; (ii) the infinite network appears above the volume fraction about 0.1. and this value is rather insensitive to the shear rate; (iii) below and above the percolation transition, the steady state viscosity depends on the shear rate γ(overdot) in the same power law.
    Type of Medium: Electronic Resource
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