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  • 1985-1989  (5)
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Material
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Study of two-body and three-body channels for the reaction of metastable helium atoms with selected atomic and molecular species (1988)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3061-3071 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the measurements of rate coefficients for excitation transfer reactions of metastable He(2 3S) atoms, produced in 0.3–4 atm of helium, with various reactants presenting a wide range of characteristics. In all cases studied, three-body reaction channels were identified with most probable values of rate coefficients lying in the range from 0.2 to 6.7×10−31 cm6 s−1, for Ne and N2O, respectively. These are generally more than one order of magnitude smaller than previously reported. The interpretation of this discrepancy in terms of a more reactive intermediate He2(Σ*) complex in dynamic equilibrium with the He(2 3S) population seems to be confirmed, and is analyzed in some detail.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.453949
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Spectroscopic study of the afterglow excited by intense electrical discharges in high-pressure helium hydrogen mixtures (1985)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 1095-1100 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this work, we report the study of afterglow plasmas with initial electron density over 1015 cm−3 excited by repetitive 3 kA, 7 ns duration discharges in He–H2 mixtures with helium pressure in the range 310–760 Torr and partial pressure of hydrogen from 20 to 400 mTorr. The afterglow radiation was emitted in He2 transitions as well as in atomic hydrogen spectral lines, with Lα being particularly intense. The ground state H concentration was estimated from the profile of the self-absorbed Lα line, indicating that dissociation of hydrogen occurs mainly in the afterglow by electron–ion recombination. He (2 3S) destruction frequencies have been determined from measurements of the optical absorption of the 2 3S→3 3P helium transition and were analyzed in terms of rate coefficients for various quenching processes. Among these, the Penning reaction with atomic hydrogen was found to be important.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.449856
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Study of two-body and three-body channels for the reaction of metastable helium atoms with nitrogen (1985)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 2274-2279 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the characterization of late time periods in the decay of metastable He(2 3S) atoms produced in 1–4 atm of helium containing up to 1400 mTorr of N2. Results have been obtained that exploit the large dynamic range and high data acquisition rates available from time resolved spectroscopic studies of preionized stripline discharges. A new value was found for the termolecular reaction of (2 3S) with N2 of 1.5×10−31 cm6 s−1 that is in good agreement with a model of collisionally induced capture. An indirect channel of reaction was also found that seems to explain the anomalously rapid and conflicting termolecular rates that were previously reported.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.448322
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Reactions of He(2 3S) with argon at atmospheric pressures (1986)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2338-2340 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.451084
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Reactivity of metastable helium molecules in atmospheric pressure afterglows (1985)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 2836-2839 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work focuses upon previously encountered problems that have impeded the understanding of the role of He2(3Σu) metastable molecules in the afterglows of electrical discharges into atmospheric pressures of helium containing admixtures of reactants. New data are reported that generally confirm the literature values for the reactivities of this species at high pressures and continue the disagreement with earlier measurements in low pressure plasmas. Results are presented for reactions with HCl and HBr for the first time. A study of systematic dependencies of rates upon molecular parameters is reported which shows that the ratio for bimolecular reactions of vibrationally excited and unexcited He2(3Σu) molecules is largely independent of the identity of the reacting partner. This provides a means for using data on the pressure dependent part of the effective rate of reaction of He(2 3S) atoms to estimate the rate coefficients for the bimolecular reactions of the more elusive He2(3Σu) molecule.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.449233
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    Paper (German National Licenses)
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