ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Alkenyl ethers react through oxygen with Me3Si+ to yield intermediates which undergo characteristic fragmentations. In the particular case of allyl ethers, the decomposing adduct undergoes several fragmentations through the allyl substituent via 6-membered transition states. The reaction between Me3Si+ and alkoxy carbonyl derivatives yields both ‘ether’ and ‘keto’ adducts, characterized by their fragmentation patterns. The ‘ether’ adducts formed from Me3Si+ and alkoxy acetones undergo the same basic eliminations as those observed for the allyl ether/Me3Si+ systems.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210160804
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