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  • 1980-1984  (8)
Material
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 3739-3745 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of magnetic iron impurity on the superconducting properties of amorphous Nb50Zr35−x Si15Fe x (x⩽4 at %) alloys was examined. Doping with an iron impurity resulted in a linear depression ofT c andH c2(T) and a decrease in $$(dH_{c2} /dT)_{T_c } $$ andρ n after reaching a maximum value at 0.5 to 1.0 at % iron. The observed decrease was about 35% forT c, 85% forH c2 at 2.0 K, 16% for $$(dH_{c2} /dT)_{T_c } $$ and 21% forρ n. Although the decrease in $$(dH_{c2} /dT)_{T_c } $$ occurs through the decrease inρ n as expected from the GLAG theory, the depression inT c caused by magnetic impurity could not be explained in terms of the GLAG theory which is applicable to Nb-Zr-Si amorphous alloys without magnetic impurity, but was interpreted as arising from the pair-breaking effect in the superconducting nature due to magnetic scattering. However, the pair-breaking effect was found to be smaller by about one-tenth for the present amorphous superconductors than for crystalline superconductors, indicating the high stability of the superconductivity of the Nb-Zr-Si-Fe alloys against the magnetic scattering arising from the magnetic impurity. The reduced magnetic field at which the reduced fluxoid pinning force exhibits a maximum value increased with iron concentration, indicative of an enhancement of fluxoid pinning force. The enhancement in fluxoid pinning force was interpreted as arising from the increase in compositional, electronic and/or magnetic fluctuations by the dope of iron impurity.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 3739-3745 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of magnetic iron impurity on the superconducting properties of amorphous Nb50Zr35−x Si15Fe x (x⩽4 at %) alloys was examined. Doping with an iron impurity resulted in a linear depression ofT c andH c2(T) and a decrease in $$(dH_{c2} /dT)_{T_c } $$ andρ n after reaching a maximum value at 0.5 to 1.0 at % iron. The observed decrease was about 35% forT c, 85% forH c2 at 2.0 K, 16% for $$(dH_{c2} /dT)_{T_c } $$ and 21% forρ n. Although the decrease in $$(dH_{c2} /dT)_{T_c } $$ occurs through the decrease inρ n as expected from the GLAG theory, the depression inT c caused by magnetic impurity could not be explained in terms of the GLAG theory which is applicable to Nb-Zr-Si amorphous alloys without magnetic impurity, but was interpreted as arising from the pair-breaking effect in the superconducting nature due to magnetic scattering. However, the pair-breaking effect was found to be smaller by about one-tenth for the present amorphous superconductors than for crystalline superconductors, indicating the high stability of the superconductivity of the Nb-Zr-Si-Fe alloys against the magnetic scattering arising from the magnetic impurity. The reduced magnetic field at which the reduced fluxoid pinning force exhibits a maximum value increased with iron concentration, indicative of an enhancement of fluxoid pinning force. The enhancement in fluxoid pinning force was interpreted as arising from the increase in compositional, electronic and/or magnetic fluctuations by the dope of iron impurity.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 17 (1982), S. 3299-3307 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A new type of refractory metal-metalloid amorphous alloys exhibiting superconductivity has been found in a binary Zr-Ge system by a modified melt-spinning technique. Specimens are in the form of continuous ribbons 1 to 2 mm wide and 0.02 to 0.03 mm thick. The germanium content in the amorphous alloys is limited to the range of 13 to 21 at%. These amorphous alloys are so ductile that no cracks are observed even after closely contacted bending test. The Vickers hardness and crystallization temperature increase from 435 to 530 DPN and from 628 to 707 K, respectively, with germanium content, and the tensile fracture strength is about 1460 MPa. Furthermore, the amorphous alloys exhibit a superconducting transition which occurs very sharply. The superconducting transition temperature (T c) increases with decreasing germanium content and reaches a maximum value of 2.88 K for Zr87Ge13. The upper critical magnetic field for Zr87Ge13 alloy was of the order of 21.8 kOe at 2.0 K and the critical current density for Zr85Ge15 alloy was about 175 A cm−2 at 1.70 K in the absence of an applied field. The upper critical field gradient atT c and the electrical resistivity at 4.2 K increase significantly from 24.6 to 31.5 kOe K−1 and from 235 to 310μΩcm, respectively, with the amount of germanium. The Ginzburg-Landau (GL) parameterк and the GL coherence length §GL (0) were estimated to be 72 to 111 and about 7.9 nm, respectively, from these experimental values by using the Ginzburg-Landau-Abrikosov-Gorkov (GLAG) theory and hence it is concluded that the Zr-Ge amorphous alloys are extremely “soft” type-II superconductor with high degree of dirtiness which possesses theT c values higher than zirconium metal, in addition to high strength combined with good ductility.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 114-126 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Superconducting amorphous alloys with high strength and good ductility have been found in rapidly quenched alloys of the Zr-Nb-Si system. These alloys were produced in a continuous ribbon form of 1 to 2 mm width and 0.02 to 0.03 mm thickness using a modified single roller quenching apparatus. The amorphous alloys were formed over the whole composition range between zirconium and niobium, but the silicon content was limited to the relatively narrow range between about 12 and 24 at%. All the amorphous alloys showed a superconducting transition whose temperature, T c, increased from 2.31 to 4.20 K with increasing niobium content or with decreasing silicon content. The upper critical magnetic field, H c2, and the critical current density, J c, for Zr15Nb70Si15 alloy were of the order of 4.5 Tesla(T) and 5.5×106 A m−2 at 1.5 K in the absence of applied field. The upper critical field gradient at T c, $$(dH_{c2} /dT)_{T_c } $$ , and the electrical resistivity at 4.2 K, ρ n, decreased from 2.89 to 2.10 T K−1 and from 2.70 to 1.80μΩm, respectively, with the amount of niobium. The Debye temperature, θ D, the electron-phonon coupling constant, λ, and the bare density of electronic states at the Fermi level, N(E f ) were calculated from the experimentally measured values of ρ n, $$(dH_{c2} /dT)_{T_c } $$ , Young's modulus and density by using the strong-coupling theories. From the comparison of T c with their calculated parameters, it was found that λ is the most dominant parameter for T c. The GL parameter, κ, and the GL coherence length, ξ GL(0), were estimated to be 70 to 100 and about 7.6 nm, respectively, from the experimental values of $$(dH_{c2} /dT)_{T_c } $$ and ρ n by using the GLAG theory and hence it is concluded that the present amorphous alloys are an extremely “dirty” type-II superconductor having a very weak flux pinning force.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Amorphous Nb-19 at% Si alloy, prepared by rapid quenching from the molten state, was annealed while being subjected to a pressure of 10 GPA. X-ray diffraction investigations on the alloy specimens quenched to ambient conditions have shown that pressure greatly alters the crystallization characteristics and the cubic A15 (Nb3Si)-phase forms in preference to the tetragonal Nb3Si-phase at temperatures in the range from 710° C to 800° C. Up to 680° C, the component atoms do not show any tendency towards ordering upon crystallization and the body-centred tetragonal solid solution forms; while, at 830° C, niobium atoms diffuse to form the body-centred cubic Nb precipitates. Superconducting properties have been measured for the single-phase A15 structure with the lattice parametera=0.5155 nm with the results that the transition temperature,T C, is 3.4 K and the temperature coefficient of the upper critical field,H C2, is 1.2 MA m−1 K−1 (15 kOe K−1).
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 17 (1982), S. 2218-2226 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The new non-equilibrium superconductor with a b c c structure has been found in rapidly quenched Zr-Si alloys. The silicon content in the b c c alloys was limited to the narrow range between 8 and 11 at%. The b c c alloys showed a superconducting transition whose temperature increased from 3.20 to 3.84 K with decreasing silicon content. The upper critical magnetic field and the critical current density for Zr92Si8 alloy were of the order of 3.58 × 106 Am−1 at 2.0 K and 3.3 × 10−2 Am−2 at 2.42 K in the absence of an applied field. The upper critical field gradient at the transition temperature and the electrical resistivity at 4.2 K were about — 1.82 × 10−1 Am−1 K−1 and about 150 μΩcm. The Ginzburg-Landau parameter κ and coherence length ξGL (0) were estimated to be about 65 and 6.3 nm, respectively, from these experimental values by using the Ginzburg-Landau-Abrikosov-Gorkov theory and hence it is concluded that the present b c c alloys are extremely “soft” type-II superconductors with a high degree of dirtiness.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The changes in the superconducting and electronic properties of amorphous Nb70Zr15Si15 and Zr85Si15 alloys with annealing were examined with an aim to evaluate the effect of structural relaxation on the superconductivity of metal-metalloid type amorphous alloys.T c rises once from 3.99 to 4.42 K on annealing at temperatures below about 473 K for the Nb-Zr-Si alloy and from 2.71 to 2.75 K at temperatures below about 373 K for the Zr-Si alloy, and with further rising annealing temperature,t d, lowers monotonically to a final relaxed value (≃3.15 K for Nb70Zr15Si15 and ≃2.49 K for Zr85Si15), which is independent of the previous thermal cycling. These results indicate that the thermal relaxation of an amorphous phase occurs through at least two stages. The lowering ofT c occurs exponentially witht d, and an activation energy for the relaxation process and the frequency of jump over the barrier were estimated to be about 2.03 eV and 2.4×1014 sec−1 for Nb70Zr15Si15 and about 1.28 eV and 1.2×1011 sec−1 for Zr85Si15, respectively. The high frequencies indicate that the relaxations occur more or less independently of each other in a non-co-operative manner. The dressed density of electronic states at the Fermi level,N(E f) (1+λ), which was calculated from the measured values ofρ n and (dH c2dT)Tc, exhibited a similar annealing temperature dependence to that ofT c. From this the change inT c on thermal relaxation was interpreted as due to the changes in λ and/orN(E f). From the depressions ofJ c(H) and fluxoid pinning force on annealing in a temperature range of 473 to 873 K, it was concluded that the structural relaxation from a less homogeneous quenched-in state to a homogeneous stable state occurred on the scale of coherence length (≃7.5 nm) during the annealing.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 55 (1984), S. 393-410 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The upper critical fieldH c2 has been measured for the superconducting amorphous alloys Zr100−x Si x withx=13, 15, and 17 over a wide temperature range down to 50 mK. Measurements for related properties, such as the depinning current densityJ p , pinning force densityF p , and flux flow resistivity ρ f , reveal that these systems are well characterized as typically soft and dirty type II superconductors with an extremely lowJ p of 1 A/cm2 andF p of 1.5×104 N/m3 ath (≡H/H c2)=0.5 andt (≡T/T c )=0.5. The temperature dependence ofH c2 is well fitted by a curve of the Werthamer-Helfand-Hohenberg theory with Maki parameter α=1.7−1.5 and spin-orbit interaction parameter λso=1−2.4. These results indicate that the Pauli spin-paramagnetic effect plays an important role in the low-temperature behavior ofH c2 in these low-T c and high-H c2 amorphous superconductors. Corrections of the electron-phonon coupling (λep=0.6) to the Pauli spin-paramagnetic limiting field lead to a reduced importance of the spin-orbit interaction effect, with λso less than 1.0. A discussion is given of the structural inhomogeneities in an amorphous phase, which are sensitively reflected in the strength of the fluxoid line pinning interaction (J p ,F p ) and are intimately related to the nonintrinsic anomaly, observed in many amorphous alloys, thatH c2 depends linearly on temperature even at low temperatures, exceeding the theoretically allowedH c2 values.
    Type of Medium: Electronic Resource
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