ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Oximate complexes of bis(cyclopentadienyl)zirconium(IV) chloride (Cp2ZrCl2 ) having the general formulae Cp2Zr(Ox), Cp2Zr(OxH)Cl and Cp2Zr(OxH)2 [where OxH2 = RC6H4C(OH)R′: NOH, R = H, Me, R′= H, Me, Et, n-Pr; PhC: N(OH)CH(OH)Ph and R″C : N(OH)N(OH): CR″, R″ = H, Me and Ph] have been synthesized by reacting bis(cyclopentadienyl)zirconium(IV) chloride with the appropriate oxime in tetrahydrofuran in the presence of triethylamine at room temperature. The complexes have been characterized by their elemental analysis, i.r. and electronic spectra, molecular weight determination, electrical conductance and magnetic measurements.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01393548
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